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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1002/ejic.201801221
|2 doi
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|a pubmed24n0987.xml
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|a eng
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| 100 |
1 |
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|a Verhoeven, Dide G A
|e verfasserin
|4 aut
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|a Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands
|b Catalytic Activity in Hydrosilylation Reactions
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 11.10.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The hydrosilylation of unsaturated compounds homogeneously catalyzed by cobalt complexes has gained considerable attention in the last years, aiming at substituting precious metal-based catalysts. In this study, the catalytic activity of well-characterized CoII and CoI complexes of the pToldpbp ligand is demonstrated in the hydrosilylation of 1-octene with phenylsilane. The CoI complex is the better precatalyst for the mentioned reaction under mild conditions, at 1 mol-% catalyst, 1 h, room temperature, and without solvent, yielding 84 % of octylphenylsilane. Investigation of the substrate scope shows lower performance of the catalyst in styrene hydrosilylation, but excellent results with allylbenzene (84 %) and acetophenone (> 99 %). This catalytic study contributes to the field of cobalt-catalyzed hydrosilylation reactions and shows the first example of catalysis employing the dpbp ligand in combination with a base metal
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|a Journal Article
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|a Cobalt
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| 650 |
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|a Cooperative catalysis
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|a Homogeneous catalysis
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| 650 |
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|a Hydrosilylation
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| 650 |
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|a Silane chemistry
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| 700 |
1 |
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|a Kwakernaak, Joost
|e verfasserin
|4 aut
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| 700 |
1 |
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|a van Wiggen, Maxime A C
|e verfasserin
|4 aut
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|a Lutz, Martin
|e verfasserin
|4 aut
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|a Moret, Marc-Etienne
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t European journal of inorganic chemistry
|d 1998
|g 2019(2019), 5 vom: 07. Feb., Seite 660-667
|w (DE-627)NLM098272756
|x 1434-1948
|7 nnns
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| 773 |
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|g volume:2019
|g year:2019
|g number:5
|g day:07
|g month:02
|g pages:660-667
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|u http://dx.doi.org/10.1002/ejic.201801221
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