Interfacial Electronic Structure Modulation of NiTe Nanoarrays with NiS Nanodots Facilitates Electrocatalytic Oxygen Evolution

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 21 vom: 04. Mai, Seite e1900430
Auteur principal: Xue, Ziqian (Auteur)
Autres auteurs: Li, Xia, Liu, Qinglin, Cai, Mengke, Liu, Kang, Liu, Min, Ke, Zhuofeng, Liu, Xialin, Li, Guangqin
Format: Article en ligne
Langue:English
Publié: 2019
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article electrocatalysis electronic structure interface engineering nickel telluride oxygen evolution reaction
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520 |a Interface engineering has been recognized as one of the most promising strategies for regulating the physical and chemical properties of materials. However, constructing well-defined nanointerfaces with efficient oxygen evolution reaction (OER) still remains a challenge. Herein, cross columnar NiTe nanoarrays supported on nickel foam are prepared. Subsequently, NiTe/NiS nanointerfaces are constructed by an ion-exchange process. Importantly, the electrocatalytic performance for the OER can be facilitated by coupling NiTe and NiS. As a result, NiTe/NiS shows excellent OER activity with an ultralow overpotential of only 257 mV at a current density of 100 mA cm-2 , and a Tafel slope of 49 mV dec-1 in 1.0 m KOH. The calculated and experimental results reveal that the strong electron interaction on nanointerfaces induces electronic structure modulation, which optimizes the binding energy of *OOH intermediates, thus improving the OER performance 
650 4 |a Journal Article 
650 4 |a electrocatalysis 
650 4 |a electronic structure 
650 4 |a interface engineering 
650 4 |a nickel telluride 
650 4 |a oxygen evolution reaction 
700 1 |a Li, Xia  |e verfasserin  |4 aut 
700 1 |a Liu, Qinglin  |e verfasserin  |4 aut 
700 1 |a Cai, Mengke  |e verfasserin  |4 aut 
700 1 |a Liu, Kang  |e verfasserin  |4 aut 
700 1 |a Liu, Min  |e verfasserin  |4 aut 
700 1 |a Ke, Zhuofeng  |e verfasserin  |4 aut 
700 1 |a Liu, Xialin  |e verfasserin  |4 aut 
700 1 |a Li, Guangqin  |e verfasserin  |4 aut 
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773 1 8 |g volume:31  |g year:2019  |g number:21  |g day:04  |g month:05  |g pages:e1900430 
856 4 0 |u http://dx.doi.org/10.1002/adma.201900430  |3 Volltext 
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