Accounting for spectroscopic effects in laser-based open-path eddy covariance flux measurements

© 2019 John Wiley & Sons Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Global change biology. - 1999. - 25(2019), 6 vom: 15. Juni, Seite 2189-2202
1. Verfasser: Burba, George (VerfasserIn)
Weitere Verfasser: Anderson, Tyler, Komissarov, Anatoly
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Global change biology
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S. CH4 CO2 GHG N2O NH3 O3 eddy covariance flux mehr... laser open-path spectroscopic effects Gases Carbon Dioxide 142M471B3J Nitrous Oxide K50XQU1029
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245 1 0 |a Accounting for spectroscopic effects in laser-based open-path eddy covariance flux measurements 
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520 |a © 2019 John Wiley & Sons Ltd. 
520 |a A significant portion of the production and consumption of trace gases (e.g. CO2 , CH4 , N2 O, NH3 , etc.) by world ecosystems occurs in areas without sufficient infrastructure or easily available grid power to run traditional closed-path flux stations. Open-path analyzer design allows such measurements with power consumption 10-150 times below present closed-path technologies, helping to considerably expand the global coverage and improve the estimates of gas emissions and budgets, informing the remote sensing and modeling communities and policy decisions, all the way to IPCC reports. Broad-band nondispersive infrared devices have been used for open-path CO2 and H2 O measurements since the late 1970s, but since recently, a growing number of new narrow-band laser-based instruments are being rapidly developed. The new design comes with its own challenges, specifically: (a) mirror contamination, and (b) uncontrolled air temperature, pressure and humidity, affecting both the gas density and the laser spectroscopy of the measurements. While the contamination can be addressed via automated cleaning, and density effects can be addressed via the Webb-Pearman-Leuning approach, the spectroscopic effects of the in situ temperature, pressure and humidity fluctuations on laser-measured densities remain a standing methodological question. Here we propose a concept accounting for such effects in the same manner as Webb et al. proposed to account for respective density effects. Derivations are provided for a general case of flux of any gas, examined using a specific example of CH4 fluxes from a commercially available analyzer, and then tested using "zero-flux" experiment. The proposed approach helps reduce errors in open-path, enclosed, and temperature- or pressure-uncontrolled closed-path laser-based flux measurements due to the spectroscopic effects from few percents to multiple folds, leading to methodological advancement and geographical expansion of the use of such systems providing reliable and consistent results for process-level studies, remote sensing and Earth modeling applications, and GHG policy decision-making 
650 4 |a Journal Article 
650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
650 4 |a CH4 
650 4 |a CO2 
650 4 |a GHG 
650 4 |a N2O 
650 4 |a NH3 
650 4 |a O3 
650 4 |a eddy covariance 
650 4 |a flux 
650 4 |a laser 
650 4 |a open-path 
650 4 |a spectroscopic effects 
650 7 |a Gases  |2 NLM 
650 7 |a Carbon Dioxide  |2 NLM 
650 7 |a 142M471B3J  |2 NLM 
650 7 |a Nitrous Oxide  |2 NLM 
650 7 |a K50XQU1029  |2 NLM 
700 1 |a Anderson, Tyler  |e verfasserin  |4 aut 
700 1 |a Komissarov, Anatoly  |e verfasserin  |4 aut 
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773 1 8 |g volume:25  |g year:2019  |g number:6  |g day:15  |g month:06  |g pages:2189-2202 
856 4 0 |u http://dx.doi.org/10.1111/gcb.14614  |3 Volltext 
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