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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.9b00262
|2 doi
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|a pubmed24n0981.xml
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|a (DE-627)NLM294365036
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|a (NLM)30811939
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|a DE-627
|b ger
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|e rakwb
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|a eng
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|a Zhang, Lei
|e verfasserin
|4 aut
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|a Synergetic Effect of Ethyl Methyl Carbonate and Trimethyl Phosphate on BF4- Intercalation into a Graphite Electrode
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Revised 20.11.2019
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a LiBF4-ethyl methyl carbonate (EMC)-based solutions have not been successfully employed in dual-ion batteries (DIBs) mainly on account of few solvated BF4- intercalations into graphite positive electrodes. In this article, trimethyl phosphate (TMP) is introduced into 1 M LiBF4-EMC solution as the electrolyte solution for DIBs, thus revealing a synergetic effect in which the discharge capacity for the anion storage using 1 M LiBF4-EMC/TMP (8:2 by vol) (ca. 26.7 mA h g-1) is far superior to that for the batteries using 1 M LiBF4-EMC (ca. 2.7 mA h g-1) or 1 M LiBF4-TMP (ca. 1.1 mA h g-1). In this case, the effects of TMP on LiBF4 in 1 M LiBF4-EMC/TMP electrolyte solutions are explored by conventional electrochemical tests, ex situ X-ray diffraction, in situ Raman spectroscopy, and nuclear magnetic resonance
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|a Journal Article
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|a Li, Jiayu
|e verfasserin
|4 aut
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1 |
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|a Huang, Yuhao
|e verfasserin
|4 aut
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1 |
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|a Zhu, Dandan
|e verfasserin
|4 aut
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1 |
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|a Wang, Hongyu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 35(2019), 11 vom: 19. März, Seite 3972-3979
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:35
|g year:2019
|g number:11
|g day:19
|g month:03
|g pages:3972-3979
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|u http://dx.doi.org/10.1021/acs.langmuir.9b00262
|3 Volltext
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|d 35
|j 2019
|e 11
|b 19
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|h 3972-3979
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