PGM-Free Cathode Catalysts for PEM Fuel Cells : A Mini-Review on Stability Challenges

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 31 vom: 01. Aug., Seite e1807615
1. Verfasser: Shao, Yuyan (VerfasserIn)
Weitere Verfasser: Dodelet, Jean-Pol, Wu, Gang, Zelenay, Piotr
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Review MNx moieties PGM-free catalysts degradation oxygen reduction platinum group metal-free catalysts
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520 |a In recent years, significant progress has been achieved in the development of platinum group metal-free (PGM-free) oxygen reduction reaction (ORR) catalysts for proton exchange membrane (PEM) fuel cells. At the same time the limited durability of these catalysts remains a great challenge that needs to be addressed. This mini-review summarizes the recent progress in understanding the main causes of instability of PGM-free ORR catalysts in acidic environments, focusing on transition metal/nitrogen codoped systems (M-N-C catalysts, M: Fe, Co, Mn), particularly MNx moiety active sites. Of several possible degradation mechanisms, demetalation and carbon oxidation are found to be the most likely reasons for M-N-C catalysts/cathodes degradation 
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700 1 |a Dodelet, Jean-Pol  |e verfasserin  |4 aut 
700 1 |a Wu, Gang  |e verfasserin  |4 aut 
700 1 |a Zelenay, Piotr  |e verfasserin  |4 aut 
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