MXene-Derived Ferroelectric Crystals

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 14 vom: 05. Apr., Seite e1806860
1. Verfasser: Tu, Shaobo (VerfasserIn)
Weitere Verfasser: Ming, Fangwang, Zhang, Junwei, Zhang, Xixiang, Alshareef, Husam N
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article MAX phase MXene-derived ferroelectricity hydrothermal synthesis single crystal
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520 |a This study demonstrates the first synthesis of MXene-derived ferroelectric crystals. Specifically, high-aspect-ratio potassium niobate (KNbO3 ) ferroelectric crystals is successfully synthesized using 2D Nb2 C, MXene, and potassium hydroxide (KOH) as the niobium and potassium source, respectively. Material analysis confirms that a KNbO3 orthorhombic phase with Amm2 symmetry is obtained. Additionally, ferroelectricity in KNbO3 is confirmed using standard ferroelectric, dielectric, and piezoresponse force microscopy measurements. The KNbO3 crystals exhibit a saturated polarization of ≈21 µC cm-2 , a remnant polarization of ≈17 µC cm-2 , and a coercive field of ≈50 kV cm-1 . This discovery illustrates that the 2D nature of MXenes can be exploited to grow ferroelectric crystals 
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700 1 |a Ming, Fangwang  |e verfasserin  |4 aut 
700 1 |a Zhang, Junwei  |e verfasserin  |4 aut 
700 1 |a Zhang, Xixiang  |e verfasserin  |4 aut 
700 1 |a Alshareef, Husam N  |e verfasserin  |4 aut 
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