Decorating g-C3N4 Nanosheets with Ti3C2 MXene Nanoparticles for Efficient Oxygen Reduction Reaction

One of the major challenges associated with fuel cells is exploring highly efficient and low-cost electrocatalysts for the oxygen reduction reaction (ORR). Herein, the feasibility of using Ti3C2 MXene nanoparticles (NPs) to enhance the electrocatalytic activity of g-C3N4 for ORR was investigated. By...

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Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 35(2019), 8 vom: 26. Feb., Seite 2909-2916
Auteur principal: Yu, Xuelian (Auteur)
Autres auteurs: Yin, Wenchao, Wang, Tao, Zhang, Yihe
Format: Article en ligne
Langue:English
Publié: 2019
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
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520 |a One of the major challenges associated with fuel cells is exploring highly efficient and low-cost electrocatalysts for the oxygen reduction reaction (ORR). Herein, the feasibility of using Ti3C2 MXene nanoparticles (NPs) to enhance the electrocatalytic activity of g-C3N4 for ORR was investigated. By varying the content of Ti3C2 NPs, a series of g-C3N4/Ti3C2 heterostructures were obtained, displaying enhanced electrocatalytic activity, including a positive shift in both onset and peak potentials toward ORR, compared to the original g-C3N4 in basic solution. We attribute the improvement to the favorable electrical conductivity of well-dispersed Ti3C2 MXene nanoparticles and also enhanced O2 adsorption due to the electronic coupling effect between g-C3N4 and Ti3C2 in the heterostructures. This work demonstrates the potential of earth-abundant MXene family materials to construct low-cost and high-performance electrocatalysts 
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700 1 |a Wang, Tao  |e verfasserin  |4 aut 
700 1 |a Zhang, Yihe  |e verfasserin  |4 aut 
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