Pinning-Free Evaporation of Sessile Droplets of Water from Solid Surfaces

Contact-line pinning is a fundamental limitation to the motion of contact lines of liquids on solid surfaces. When a sessile droplet evaporates, contact-line pinning typically results in either a stick-slip evaporation mode, where the contact line pins and depins from the surface in an uncontrolled...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 8 vom: 26. Feb., Seite 2989-2996
1. Verfasser: Armstrong, Steven (VerfasserIn)
Weitere Verfasser: McHale, Glen, Ledesma-Aguilar, Rodrigo, Wells, Gary G
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Contact-line pinning is a fundamental limitation to the motion of contact lines of liquids on solid surfaces. When a sessile droplet evaporates, contact-line pinning typically results in either a stick-slip evaporation mode, where the contact line pins and depins from the surface in an uncontrolled manner, or a constant contact-area mode with a pinned contact line. Pinning prevents the observation of the quasi-equilibrium constant contact-angle mode of evaporation, which has never been observed for sessile droplets of water directly resting on a smooth, nontextured, solid surface. Here, we report the evaporation of a sessile droplet from a flat glass substrate treated with a smooth, slippery, omni-phobic covalently attached liquid-like coating. Our characterization of the surfaces shows high contact line mobility with an extremely low contact-angle hysteresis of ∼1° and reveals a step change in the value of the contact angle from 101° to 105° between a relative humidity (RH) of 30 and 40%, in a manner reminiscent of the transition observed in a type V adsorption isotherm. We observe the evaporation of small sessile droplets in a chamber held at a constant temperature, T = (25.0 ± 0.1) °C and at constant RH across the range RH = 10-70%. In all cases, a constant contact-angle mode of evaporation is observed for most of the evaporation time. Furthermore, we analyze the evaporation sequences using the Picknett and Bexon ideal constant contact-angle mode for diffusion-limited evaporation. The resulting estimate for the diffusion coefficient, DE, of water vapor in air of DE = (2.44 ± 0.48) × 10-5 m2 s-1 is accurate to within 2% of the value reported in the literature, thus validating the constant contact-angle mode of the diffusion-limited evaporation model 
650 4 |a Journal Article 
700 1 |a McHale, Glen  |e verfasserin  |4 aut 
700 1 |a Ledesma-Aguilar, Rodrigo  |e verfasserin  |4 aut 
700 1 |a Wells, Gary G  |e verfasserin  |4 aut 
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