Stabilization of a Highly Concentrated Colloidal Suspension of Pristine Metallic Nanoparticles

A colloidal suspension containing a high concentration of metallic nanoparticles (NPs) finds potential applications in flexible electronic printing, nanofluids, healthcare, antifouling coating, and so on. Here, we demonstrate a generic, easily scalable, simple, and contamination-free cryogenic tempe...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 7 vom: 19. Feb., Seite 2668-2673
1. Verfasser: Katiyar, Nirmal Kumar (VerfasserIn)
Weitere Verfasser: Biswas, Krishanu, Tiwary, Chandra Sekhar, Machado, Leonardo Dantas, Gupta, Raju Kumar
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a A colloidal suspension containing a high concentration of metallic nanoparticles (NPs) finds potential applications in flexible electronic printing, nanofluids, healthcare, antifouling coating, and so on. Here, we demonstrate a generic, easily scalable, simple, and contamination-free cryogenic temperature grinding method, which can effectively be used to prepare pristine NPs that can be stabilized in polar liquids in high concentrations. These surfactant-free pristine NPs have been found to remain dispersed in different polar liquids (CH3OH, C2H5OH, glycol, etc.) for weeks. The long-term stability of the NPs in these liquids has been investigated using zeta potential, in situ Fourier transform infrared spectroscopy, indicating electrostatic stabilization for ultrapure, surfactant-free NPs. Furthermore, stabilization of the NPs has been probed with detailed calculations using the Derjaguin Landau Verwey Overbeek theory as well as atomistic molecular dynamics simulation (MD). Experimental measurements along with theoretical calculations categorically indicate that the electrostatic energy is helping these NPs to be stabilized in a polar liquid 
650 4 |a Journal Article 
700 1 |a Biswas, Krishanu  |e verfasserin  |4 aut 
700 1 |a Tiwary, Chandra Sekhar  |e verfasserin  |4 aut 
700 1 |a Machado, Leonardo Dantas  |e verfasserin  |4 aut 
700 1 |a Gupta, Raju Kumar  |e verfasserin  |4 aut 
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