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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201805930
|2 doi
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|a pubmed24n0976.xml
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|a (DE-627)NLM292996039
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|a (NLM)30672039
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|a DE-627
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|e rakwb
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|a eng
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|a Du, Aobing
|e verfasserin
|4 aut
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|a A Crosslinked Polytetrahydrofuran-Borate-Based Polymer Electrolyte Enabling Wide-Working-Temperature-Range Rechargeable Magnesium Batteries
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 13.03.2019
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a A polymer-based magnesium (Mg) electrolyte is vital for boosting the development of high-safety and flexible Mg batteries by virtue of its enormous advantages, such as significantly improved safety, potentially high energy density, ease of fabrication, and structural flexibility. Herein, a novel polytetrahydrofuran-borate-based gel polymer electrolyte coupling with glass fiber is synthesized via an in situ crosslinking reaction of magnesium borohydride [Mg(BH4 )2 ] and hydroxyl-terminated polytetrahydrofuran. This gel polymer electrolyte exhibits reversible Mg plating/stripping performance, high Mg-ion conductivity, and remarkable Mg-ion transfer number. The Mo6 S8 /Mg batteries assembled with this gel polymer electrolyte not only work well at wide temperature range (-20 to 60 °C) but also display unprecedented improvements in safety issues without suffering from internal short-circuit failure even after a cutting test. This in situ crosslinking approach toward exploiting the Mg-polymer electrolyte provides a promising strategy for achieving large-scale application of Mg-metal batteries
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|a Journal Article
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|a borates
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|a in situ crosslinking reaction
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|a magnesium batteries
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|a polymer electrolytes
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|a polytetrahydrofuran
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|a Zhang, Huanrui
|e verfasserin
|4 aut
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|a Zhang, Zhonghua
|e verfasserin
|4 aut
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|a Zhao, Jingwen
|e verfasserin
|4 aut
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|a Cui, Zili
|e verfasserin
|4 aut
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|a Zhao, Yimin
|e verfasserin
|4 aut
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|a Dong, Shanmu
|e verfasserin
|4 aut
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|a Wang, Longlong
|e verfasserin
|4 aut
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|a Zhou, Xinhong
|e verfasserin
|4 aut
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|a Cui, Guanglei
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 11 vom: 23. März, Seite e1805930
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:31
|g year:2019
|g number:11
|g day:23
|g month:03
|g pages:e1805930
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|u http://dx.doi.org/10.1002/adma.201805930
|3 Volltext
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