Hollow Functional Materials Derived from Metal-Organic Frameworks : Synthetic Strategies, Conversion Mechanisms, and Electrochemical Applications

© 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 31(2019), 11 vom: 20. März, Seite e1804903
1. Verfasser: Cai, Ze-Xing (VerfasserIn)
Weitere Verfasser: Wang, Zhong-Li, Kim, Jeonghun, Yamauchi, Yusuke
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2019
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Review batteries conversion mechanisms electrocatalysis hollow structures metal-organic frameworks
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520 |a Hollow materials derived from metal-organic frameworks (MOFs), by virtue of their controllable configuration, composition, porosity, and specific surface area, have shown fascinating physicochemical properties and widespread applications, especially in electrochemical energy storage and conversion. Here, the recent advances in the controllable synthesis are discussed, mainly focusing on the conversion mechanisms from MOFs to hollow-structured materials. The synthetic strategies of MOF-derived hollow-structured materials are broadly sorted into two categories: the controllable synthesis of hollow MOFs and subsequent pyrolysis into functional materials, and the controllable conversion of solid MOFs with predesigned composition and morphology into hollow structures. Based on the formation processes of hollow MOFs and the conversion processes of solid MOFs, the synthetic strategies are further conceptually grouped into six categories: template-mediated assembly, stepped dissolution-regrowth, selective chemical etching, interfacial ion exchange, heterogeneous contraction, and self-catalytic pyrolysis. By analyzing and discussing 14 types of reaction processes in detail, a systematic mechanism of conversion from MOFs to hollow-structured materials is exhibited. Afterward, the applications of these hollow structures as electrode materials for lithium-ion batteries, hybrid supercapacitors, and electrocatalysis are presented. Finally, an outlook on the emergent challenges and future developments in terms of their controllable fabrications and electrochemical applications is further discussed 
650 4 |a Journal Article 
650 4 |a Review 
650 4 |a batteries 
650 4 |a conversion mechanisms 
650 4 |a electrocatalysis 
650 4 |a hollow structures 
650 4 |a metal-organic frameworks 
700 1 |a Wang, Zhong-Li  |e verfasserin  |4 aut 
700 1 |a Kim, Jeonghun  |e verfasserin  |4 aut 
700 1 |a Yamauchi, Yusuke  |e verfasserin  |4 aut 
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