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231225s2019 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201805293
|2 doi
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|a pubmed25n0973.xml
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|a eng
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|a Kim, Jin Yeong
|e verfasserin
|4 aut
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|a Hydrogen Isotope Separation in Confined Nanospaces
|b Carbons, Zeolites, Metal-Organic Frameworks, and Covalent Organic Frameworks
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|c 2019
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a One of the greatest challenges of modern separation technology is separating isotope mixtures in high purity. The separation of hydrogen isotopes can create immense economic value by producing valuable deuterium (D) and tritium (T), which are irreplaceable for various industrial and scientific applications. However, current separation methods suffer from low separation efficiency owing to the similar chemical properties of isotopes; thus, high-purity isotopes are not easily achieved. Recently, nanoporous materials have been proposed as promising candidates and are supported by a newly proposed separation mechanism, i.e., quantum effects. Herein, the fundamentals of the quantum sieving effect of hydrogen isotopes in nanoporous materials are discussed, which are mainly kinetic quantum sieving and chemical-affinity quantum sieving, including the recent advances in the analytical techniques. As examples of nanoporous materials, carbons, zeolites, metal-organic frameworks, and covalent organic frameworks are addressed from computational and experimental standpoints. Understanding the quantum sieving effect in nanospaces and the tailoring of porous materials based on it will open up new opportunities to develop a highly efficient and advanced isotope separation systems
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|a Journal Article
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|a Review
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|a chemical affinity quantum sieving
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|a hydrogen isotopes
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|a isotope separation
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| 650 |
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|a kinetic quantum sieving
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| 650 |
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4 |
|a porous materials
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|a Oh, Hyunchul
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Moon, Hoi Ri
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 31(2019), 20 vom: 05. Mai, Seite e1805293
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:31
|g year:2019
|g number:20
|g day:05
|g month:05
|g pages:e1805293
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|u http://dx.doi.org/10.1002/adma.201805293
|3 Volltext
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