Precise Self-Assembly and Controlled Catalysis of Thermoresponsive Core-Satellite Multicomponent Hybrid Nanoparticles
The construction of multicomponent hybrid nanomaterials with well-controlled architecture, especially bearing an ordered homogeneity and distribution of the subunits with tunable functions, is a key challenge in chemistry and material science. Herein, we reported a versatile and novel strategy to fa...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 35(2019), 1 vom: 08. Jan., Seite 266-275 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2019
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, Non-U.S. Gov't |
| Zusammenfassung: | The construction of multicomponent hybrid nanomaterials with well-controlled architecture, especially bearing an ordered homogeneity and distribution of the subunits with tunable functions, is a key challenge in chemistry and material science. Herein, we reported a versatile and novel strategy to fabricate core-satellite multicomponent nanostructures with tunable interparticle distances and catalysis properties by the combination of surface-initiated reversible addition-fragmentation chain transfer (SI-RAFT) polymerization and self-assembly. The arrangement and interparticle distance of gold satellites could be precisely tuned by the SI-RAFT polymerization process and the feeding ratio of gold nanoparticles (AuNPs) and the core nanoparticle. It is worth to note that multilayered core-satellite nanostructures have been fabricated by a high-feeding ratio of AuNPs and magnetite NP (MNP)SiO2-PNIPAm. Notably, the core-satellite MNP@SiO2-PNIPAm-Au nanoparticles exhibited excellent thermoresponsive behaviors with the change of temperature. Furthermore, the catalytic efficiency of MNP@SiO2-PNIPAm-Au nanoparticles via the reduction of 4-nitrophenol to 4-aminophenol can be well modulated by the nanoparticle size, temperature, and polymer feed ratio. This strategy for precise construction of core-satellite nanostructures would open a new pathway to construct multicomponent functional nanostructures |
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| Beschreibung: | Date Revised 20.11.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.8b03345 |