Iron oxide nanoparticles as heterogeneous electro-Fenton catalysts for the removal of AR18 azo dye

Heterogeneous electro-Fenton mineralization of Acid Red 18 (AR18) in aqueous solution was studied with magnetite Fe3O4 (MNPs) and haematite Fe2O3 (HNPs) nanoparticles as catalysts. High mineralization yields of AR18 were obtained with magnetite, 81% TOC removal after 180 min of electrolysis in 40 mg...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Environmental technology. - 1993. - 41(2020), 16 vom: 02. Juni, Seite 2146-2153
1. Verfasser: Ben Hafaiedh, Nouha (VerfasserIn)
Weitere Verfasser: Fourcade, Florence, Bellakhal, Nizar, Amrane, Abdeltif
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Iron oxides nanoparticles azo dye electro-Fenton heterogeneous hydroxyl radicals Azo Compounds Ferric Compounds Water Pollutants, Chemical ferric oxide mehr... 1K09F3G675 Hydrogen Peroxide BBX060AN9V
LEADER 01000caa a22002652 4500
001 NLM291517838
003 DE-627
005 20250224115028.0
007 cr uuu---uuuuu
008 231225s2020 xx |||||o 00| ||eng c
024 7 |a 10.1080/09593330.2018.1557258  |2 doi 
028 5 2 |a pubmed25n0971.xml 
035 |a (DE-627)NLM291517838 
035 |a (NLM)30521420 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Ben Hafaiedh, Nouha  |e verfasserin  |4 aut 
245 1 0 |a Iron oxide nanoparticles as heterogeneous electro-Fenton catalysts for the removal of AR18 azo dye 
264 1 |c 2020 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 29.05.2020 
500 |a Date Revised 29.05.2020 
500 |a published: Print-Electronic 
500 |a Citation Status MEDLINE 
520 |a Heterogeneous electro-Fenton mineralization of Acid Red 18 (AR18) in aqueous solution was studied with magnetite Fe3O4 (MNPs) and haematite Fe2O3 (HNPs) nanoparticles as catalysts. High mineralization yields of AR18 were obtained with magnetite, 81% TOC removal after 180 min of electrolysis in 40 mg L-1 Fe3O4, pH 3.0, at 50 mA of current intensity and in 50 mM Na2SO4. In order to explain the obtained mineralization yield achieved with MNPs, the quantification of hydrogen peroxide (H2O2), hydroxyl radical (•OH) and iron leaching were performed at 50 and 100 mA. From the high iron concentration found in the bulk solution and the slight impact of the catalyst mass concentration on TOC removal, the formation of hydroxyl radicals occurs mainly through homogeneous process. In the presence of hydroxyl radical scavenger, degradation remained total after 15 min showing the involvement of a direct electrochemical oxidation of the dye at the electrode surface. The hydroxyl radical oxidation is responsible for at least 50% of mineralization 
650 4 |a Journal Article 
650 4 |a Iron oxides nanoparticles 
650 4 |a azo dye 
650 4 |a electro-Fenton 
650 4 |a heterogeneous 
650 4 |a hydroxyl radicals 
650 7 |a Azo Compounds  |2 NLM 
650 7 |a Ferric Compounds  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a ferric oxide  |2 NLM 
650 7 |a 1K09F3G675  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
650 7 |a BBX060AN9V  |2 NLM 
700 1 |a Fourcade, Florence  |e verfasserin  |4 aut 
700 1 |a Bellakhal, Nizar  |e verfasserin  |4 aut 
700 1 |a Amrane, Abdeltif  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 41(2020), 16 vom: 02. Juni, Seite 2146-2153  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnns 
773 1 8 |g volume:41  |g year:2020  |g number:16  |g day:02  |g month:06  |g pages:2146-2153 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2018.1557258  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 41  |j 2020  |e 16  |b 02  |c 06  |h 2146-2153