Steam Explosion in alkaline medium for gelatine extraction from chromium-tanned leather wastes : time reduction and process optimization

Alkaline hydrolysis of chromium-tanned leather wastes (CTLW) is a well-known process that allows the extraction of its most valuable portion: the protein. However, alkaline hydrolysis is time-consuming. It usually takes from 2 to 10 h to be completed. In this work, alkaline hydrolysis was performed...

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Veröffentlicht in:Environmental technology. - 1993. - 41(2020), 14 vom: 12. Juni, Seite 1857-1866
1. Verfasser: Scopel, Bianca Santinon (VerfasserIn)
Weitere Verfasser: Restelatto, Danielle, Baldasso, Camila, Dettmer, Aline, Campomanes Santana, Ruth Marlene
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2020
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Steam explosion extraction yield gelatine leather waste processing time reduction Steam Chromium 0R0008Q3JB Gelatin 9000-70-8
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520 |a Alkaline hydrolysis of chromium-tanned leather wastes (CTLW) is a well-known process that allows the extraction of its most valuable portion: the protein. However, alkaline hydrolysis is time-consuming. It usually takes from 2 to 10 h to be completed. In this work, alkaline hydrolysis was performed in a steam explosion reactor, using CaO as the alkalinizing agent and aiming at a short-time process. Three different temperatures and residence times were tested: 130, 140, and 150°C; 5, 10, and 15 min. When performed at 140°C for 10 min, the steam explosion in alkaline medium resulted in the optimum combination of protein extraction yield (30%) and gelatine quality (viscosity of 2.4 cP at 25°C in a 24.6 g/L protein solution - 39 kDa of molecular mass [Formula: see text]w). Not only a high extraction yield was achieved, but when compared to traditional methods, steam explosion in alkaline medium reduced the process time by a factor that varied from 12 to 36 times. It also reduced chromium content in the gelatine by a factor that varied from 16 to 96 times. Finally, to produce a high quality product, the ash content of the gelatine was reduced from 11.8% (dry basis) to 1.2% (dry basis) through diafiltration. This purification allows the application of the gelatine, for example, in the production of polymeric films 
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650 4 |a extraction yield 
650 4 |a gelatine 
650 4 |a leather waste 
650 4 |a processing time reduction 
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650 7 |a Chromium  |2 NLM 
650 7 |a 0R0008Q3JB  |2 NLM 
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700 1 |a Restelatto, Danielle  |e verfasserin  |4 aut 
700 1 |a Baldasso, Camila  |e verfasserin  |4 aut 
700 1 |a Dettmer, Aline  |e verfasserin  |4 aut 
700 1 |a Campomanes Santana, Ruth Marlene  |e verfasserin  |4 aut 
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