Surface with Reversible Green-Light-Switched Wettability by Donor-Acceptor Stenhouse Adducts

In this report, we designed surfaces with reversible green-light-switched wettability via donor-acceptor Stenhouse adducts (DASAs). Photoresponsive micro/nanoparticles were prepared by coating the surfaces of silica micro/nanoparticles with polydopamine and then postmodifying with DASA molecules. Th...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 50 vom: 18. Dez., Seite 15537-15543
1. Verfasser: Zhao, Haiquan (VerfasserIn)
Weitere Verfasser: Wang, Dongsheng, Fan, Yue, Ren, Mingrui, Dong, Shumin, Zheng, Yonghao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a In this report, we designed surfaces with reversible green-light-switched wettability via donor-acceptor Stenhouse adducts (DASAs). Photoresponsive micro/nanoparticles were prepared by coating the surfaces of silica micro/nanoparticles with polydopamine and then postmodifying with DASA molecules. Then, the particles were immobilized on a glass substrate surfaces either with double-sided adhesive tape or cross-linking poly(dimethylsiloxane). Silica micro/nanoparticles with various diameters (0.2, 2.5, and 85 μm) were used to fabricate the photoresponsive surface. Green light irradiation switches the hydrophobic linear DASA to a hydrophilic cyclic isomer, which further increases the wettability and contact angle hysteresis on the surface. On the other hand, heating (100 °C) induces the cyclic-to-linear isomerization of DASA molecules and switches the surface back to hydrophobic. The wettability of the DASA-modified surface is reversible under alternate green light irradiation and heating 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Wang, Dongsheng  |e verfasserin  |4 aut 
700 1 |a Fan, Yue  |e verfasserin  |4 aut 
700 1 |a Ren, Mingrui  |e verfasserin  |4 aut 
700 1 |a Dong, Shumin  |e verfasserin  |4 aut 
700 1 |a Zheng, Yonghao  |e verfasserin  |4 aut 
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