Metal-Organic Framework-Assisted Construction of TiO2/Co3O4 Highly Ordered Necklace-like Heterostructures for Enhanced Ethanol Vapor Sensing Performance

In this work, we report a metal-organic framework (MOF)-assisted strategy to synthesize necklace-like TiO2/Co3O4 nanofibers with highly ordered heterostructures via a facile approach including electrospinning and subsequent calcination. Polycrystalline TiO2 nanofibers and Co3O4 nanocages are consumm...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 48 vom: 04. Dez., Seite 14577-14585
1. Verfasser: Zhang, Tian (VerfasserIn)
Weitere Verfasser: Tang, Xing, Zhang, Jian, Zhou, Tingting, Wang, Hao, Wu, Congyi, Xia, Xianping, Xie, Changsheng, Zeng, Dawen
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a In this work, we report a metal-organic framework (MOF)-assisted strategy to synthesize necklace-like TiO2/Co3O4 nanofibers with highly ordered heterostructures via a facile approach including electrospinning and subsequent calcination. Polycrystalline TiO2 nanofibers and Co3O4 nanocages are consummately interconnected to form a highly ordered heterogeneous nanostructure, which can be of benefit for precisely accommodating the interface resistance of the p-n heterojunctions and the future realization of improved material performance. The ethanol-gas-sensing investigation showed that TiO2/Co3O4 nanofiber sensors exhibited a strong ethanol response ( Rair/ Rgas -1 = 16.7 150 ppm) and a low operating temperature of 150 °C. The sensing enhancement mechanism of the TiO2/Co3O4 nanofibers is related to the formation of heterojunctions at interfaces and the high catalytic activity of MOF-derived Co3O4. Furthermore, this versatile method is a promising approach to constructing ordered heterostructures and extending the MOF-based heterogeneous materials toward wide applications 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Tang, Xing  |e verfasserin  |4 aut 
700 1 |a Zhang, Jian  |e verfasserin  |4 aut 
700 1 |a Zhou, Tingting  |e verfasserin  |4 aut 
700 1 |a Wang, Hao  |e verfasserin  |4 aut 
700 1 |a Wu, Congyi  |e verfasserin  |4 aut 
700 1 |a Xia, Xianping  |e verfasserin  |4 aut 
700 1 |a Xie, Changsheng  |e verfasserin  |4 aut 
700 1 |a Zeng, Dawen  |e verfasserin  |4 aut 
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