Thermally Induced Oxidation of [FeII(tacn)2](OTf)2 (tacn = 1,4,7-triazacyclononane)
We previously reported the spin-crossover (SC) properties of [FeII(tacn)2](OTf)2 (1) (tacn = 1,4,7-triazacyclononane) [Eur. J. Inorg. Chem. 2013, 2115]. Upon heating under dynamic vacuum, 1 undergoes oxidation to generate a low spin iron(III) complex. The oxidation of the iron center was found to be...
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Bibliographische Detailangaben
Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2017(2017), 46 vom: 15. Dez., Seite 5529-5535
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1. Verfasser: |
Li, Jia
(VerfasserIn) |
Weitere Verfasser: |
Banerjee, Atanu,
Preston, Debra R,
Shay, Brian J,
Adhikary, Amitiva,
Sevilla, Michael D,
Loloee, Reza,
Staples, Richard J,
Chavez, Ferman A |
Format: | Online-Aufsatz
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Sprache: | English |
Veröffentlicht: |
2017
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Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry
|
Schlagworte: | Journal Article
DFT
EPR
Iron
Magnetic Properties
Oxidation |