XAS/DRIFTS/MS spectroscopy for time-resolved operando investigations at high temperature

The combination of complementary techniques in the characterization of catalysts under working conditions is a very powerful tool for an accurate and in-depth comprehension of the system investigated. In particular, X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance infrared Fourie...

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Veröffentlicht in:Journal of synchrotron radiation. - 1994. - 25(2018), Pt 6 vom: 01. Nov., Seite 1745-1752
1. Verfasser: Agostini, G (VerfasserIn)
Weitere Verfasser: Meira, D, Monte, M, Vitoux, H, Iglesias-Juez, A, Fernández-García, M, Mathon, O, Meunier, F, Berruyer, G, Perrin, F, Pasternak, S, Mairs, T, Pascarelli, S, Gorges, B
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Journal of synchrotron radiation
Schlagworte:Journal Article combination XAS/DRIFT/MS high temperature operando measurements small-dead-volume cells
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520 |a The combination of complementary techniques in the characterization of catalysts under working conditions is a very powerful tool for an accurate and in-depth comprehension of the system investigated. In particular, X-ray absorption spectroscopy (XAS) coupled with diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and mass spectroscopy (MS) is a powerful combination since XAS characterizes the main elements of the catalytic system (selecting the absorption edge) and DRIFTS monitors surface adsorbates while MS enables product identification and quantification. In the present manuscript, a new reactor cell and an experimental setup optimized to perform time-resolved experiments on heterogeneous catalysts under working conditions are reported. A key feature of this setup is the possibility to work at high temperature and pressure, with a small cell dead volume. To demonstrate these capabilities, performance tests with and without X-rays are performed. The effective temperature at the sample surface, the speed to purge the gas volume inside the cell and catalytic activity have been evaluated to demonstrate the reliability and usefulness of the cell. The setup capability of combining XAS, DRIFTS and MS spectroscopies is demonstrated in a time-resolved experiment, following the reduction of NO by Rh nanoparticles supported on alumina 
650 4 |a Journal Article 
650 4 |a combination XAS/DRIFT/MS 
650 4 |a high temperature 
650 4 |a operando measurements 
650 4 |a small-dead-volume cells 
700 1 |a Meira, D  |e verfasserin  |4 aut 
700 1 |a Monte, M  |e verfasserin  |4 aut 
700 1 |a Vitoux, H  |e verfasserin  |4 aut 
700 1 |a Iglesias-Juez, A  |e verfasserin  |4 aut 
700 1 |a Fernández-García, M  |e verfasserin  |4 aut 
700 1 |a Mathon, O  |e verfasserin  |4 aut 
700 1 |a Meunier, F  |e verfasserin  |4 aut 
700 1 |a Berruyer, G  |e verfasserin  |4 aut 
700 1 |a Perrin, F  |e verfasserin  |4 aut 
700 1 |a Pasternak, S  |e verfasserin  |4 aut 
700 1 |a Mairs, T  |e verfasserin  |4 aut 
700 1 |a Pascarelli, S  |e verfasserin  |4 aut 
700 1 |a Gorges, B  |e verfasserin  |4 aut 
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