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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201804647
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|a eng
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|a Savagian, Lisa R
|e verfasserin
|4 aut
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|a Balancing Charge Storage and Mobility in an Oligo(Ether) Functionalized Dioxythiophene Copolymer for Organic- and Aqueous- Based Electrochemical Devices and Transistors
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 12.12.2018
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|a Date Revised 15.01.2021
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|a published: Print-Electronic
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|a ErratumIn: Adv Mater. 2020 Sep;32(36):e2004250. doi: 10.1002/adma.202004250. - PMID 33448510
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a This work presents a soluble oligo(ether)-functionalized propylenedioxythiophene (ProDOT)-based copolymer as a versatile platform for a range of high-performance electrochemical devices, including organic electrochemical transistors (OECTs), electrochromic displays, and energy-storage devices. This polymer exhibits dual electroactivity in both aqueous and organic electrolyte systems, redox stability for thousands of redox cycles, and charge-storage capacity exceeding 80 F g-1 . As an electrochrome, this material undergoes full colored-to-colorless optical transitions on rapid time scales (<2 s) and impressive electrochromic contrast (Δ%T > 70%). Incorporation of the polymer into OECTs yields accumulation-mode devices with an ION/OFF current ratio of 105 , high transconductance without post-treatments, as well as competitive hole mobility and volumetric capacitance, making it an attractive candidate for biosensing applications. In addition to being the first ProDOT-based OECT active material reported to date, this is also the first reported OECT material synthesized via direct(hetero)arylation polymerization, which is a highly favorable polymerization method when compared to commonly used Stille cross-coupling. This work provides a demonstration of how a single ProDOT-based polymer, prepared using benign polymerization chemistry and functionalized with highly polar side chains, can be used to access a range of highly desirable properties and performance metrics relevant to electrochemical, optical, and bioelectronic applications
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|a Journal Article
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|a bioelectronics
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|a charge storage
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|a dioxythiophenes
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|a electrochromism
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|a organic electrochemical transistors
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|a Österholm, Anna M
|e verfasserin
|4 aut
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|a Ponder, James F
|c Jr
|e verfasserin
|4 aut
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| 700 |
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|a Barth, Katrina J
|e verfasserin
|4 aut
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|a Rivnay, Jonathan
|e verfasserin
|4 aut
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| 700 |
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|a Reynolds, John R
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
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|g 30(2018), 50 vom: 30. Dez., Seite e1804647
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