CNT Interwoven Nitrogen and Oxygen Dual-Doped Porous Carbon Nanosheets as Free-Standing Electrodes for High-Performance Na-Se and K-Se Flexible Batteries

CNT Interwoven Nitrogen and Oxygen Dual-Doped Porous Carbon Nanosheets as Free-Standing Electrodes for High-Performance Na-Se and K-Se Flexible Batteries

© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 30(2018), 49 vom: 09. Dez., Seite e1805234
1. Verfasser: Yao, Yu (VerfasserIn)
Weitere Verfasser: Chen, Minglong, Xu, Rui, Zeng, Sifan, Yang, Hai, Ye, Shufen, Liu, Fanfan, Wu, Xiaojun, Yu, Yan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article K-Se batteries Na-Se batteries biomass carbon dual-doping post-lithium ion batteries
Beschreibung
Zusammenfassung:© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Na-Se and K-Se batteries are attractive as a stationary energy storage system because of much abundant resources of Na and K in the Earth's crust. As the alloy-type Se has a severe pulverization issue, one critical challenge to develop advanced Na-Se and K-Se batteries is to explore a highly efficient and stable Se-based cathode. Herein, a flexible free-standing Se/carbon composite film is prepared by encapsulation of Se into a carbon nanotube (CNT) interwoven N,O dual-doped porous carbon nanosheet (SeNOPC-CNT). The 3D interconnected CNT uniformly wrapped on the N,O dual-doped porous carbon skeletons improves the flexibility and offers an interconnected conductive pathway for rapid ionic/electronic transport. In addition, the N,O dual-doping significantly enhances the chemical affinity and adhesion between Nax Se/Kx Se (0 < x ≤ 2) and porous carbon, which is confirmed by density functional theory calculation. When used as the cathode in Na-Se batteries, the Se@NOPC-CNT delivers a remarkable reversible capacity of 400 mA h g-1 at 1 A g-1 after 2000 cycles with a 0.008% capacity decay per cycle. For K-Se batteries, it also exhibits an excellent cycling stability (335 mA h g-1 after 700 cycles at 0.8 A g-1 ). This unique design may open an avenue for practical application of flexible Na-Se and K-Se batteries
Beschreibung:Date Completed 17.12.2018
Date Revised 01.10.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201805234