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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201804684
|2 doi
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|a pubmed25n0963.xml
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|a (DE-627)NLM28912512X
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|a (NLM)30276879
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Liang, Jianwen
|e verfasserin
|4 aut
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|a In Situ Li3 PS4 Solid-State Electrolyte Protection Layers for Superior Long-Life and High-Rate Lithium-Metal Anodes
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 08.11.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a A thin and adjustable Li3 PS4 (LPS) solid-state electrolyte protection layer on the surface of Li is proposed to address the dynamic plating/stripping process of Li metal. The LPS interlayer is formed by an in situ and self-limiting reaction between P4 S16 and Li in N-methyl-2-pyrrolidone. By increasing the concentration of P4 S16 , the thickness of the LPS layer can be adjusted up to 60 nm. Due to the high ionic conductivity and low electrochemical activity of Li3 PS4 , the intimate protection layer of LPS can not only prevent the formation of Li dendrites, but also reduces parasitic side reactions and improves the electrochemical performance. As a result, symmetric cells with the LPS protection layer can deliver stable Li plating/stripping for 2000 h. Full cells assembled with the LPS-protected Li exhibit two times higher capacity retention in Li-S batteries (≈800 mAh g-1 ) at 5 A g-1 for over 400 cycles compared to their bare Li counterparts. Furthermore, high rate performances can be achieved with Li-LPS/LiCoO2 cells, which are capable of cycling at rates as high as 20 C. This innovative and scalable approach to stabilizing the Li anode can serve as a basis for the development of next-generation high-performance lithium-metal batteries
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|a Journal Article
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|a Li3PS4
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|a lithium batteries
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|a lithium-metal anodes
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|a solid-state electrolytes
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|a surface isolation layer
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|a Li, Xiaona
|e verfasserin
|4 aut
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|a Zhao, Yang
|e verfasserin
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|a Goncharova, Lyudmila V
|e verfasserin
|4 aut
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|a Wang, Gongming
|e verfasserin
|4 aut
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|a Adair, Keegan R
|e verfasserin
|4 aut
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|a Wang, Changhong
|e verfasserin
|4 aut
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| 700 |
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|a Li, Ruying
|e verfasserin
|4 aut
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|a Zhu, Yongchun
|e verfasserin
|4 aut
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|a Qian, Yitai
|e verfasserin
|4 aut
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|a Zhang, Li
|e verfasserin
|4 aut
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|a Yang, Rong
|e verfasserin
|4 aut
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|a Lu, Shigang
|e verfasserin
|4 aut
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|a Sun, Xueliang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 45 vom: 30. Nov., Seite e1804684
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:30
|g year:2018
|g number:45
|g day:30
|g month:11
|g pages:e1804684
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|u http://dx.doi.org/10.1002/adma.201804684
|3 Volltext
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