One-Pot Gram-Scale Synthesis of Hydrogen-Terminated Silicon Nanoparticles
Silicon nanoparticles (Si NPs) are highly attractive materials for typical quantum dots functions, such as in light-emitting and bioimaging applications, owing to silicon's intrinsic merits of minimal toxicity, low cost, high abundance, and easy and highly stable functionalization. Especially n...
| Veröffentlicht in: | Chemistry of materials : a publication of the American Chemical Society. - 1998. - 30(2018), 18 vom: 25. Sept., Seite 6503-6512 |
|---|---|
| 1. Verfasser: | |
| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2018
|
| Zugriff auf das übergeordnete Werk: | Chemistry of materials : a publication of the American Chemical Society |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Silicon nanoparticles (Si NPs) are highly attractive materials for typical quantum dots functions, such as in light-emitting and bioimaging applications, owing to silicon's intrinsic merits of minimal toxicity, low cost, high abundance, and easy and highly stable functionalization. Especially nonoxidized Si NPs with a covalently bound coating serve well in these respects, given the minimization of surface defects upon hydrosilylation of H-terminated Si NPs. However, to date, methods to obtain such H-terminated Si NPs are still not easy. Herein, we report a new synthetic method to produce size-tunable robust, highly crystalline H-terminated Si NPs (4-9 nm) using microwave irradiation within 5 min at temperatures between 25 and 200 °C and their further covalent functionalization. The key step to obtain highly fluorescent (quantum yield of 7-16%) green-red Si NPs in one simple step is the reduction of triethoxysilane and (+)-sodium l-ascorbate, yielding routinely ∼1 g of H-Si NPs via a highly scalable route in 5-15 min. Subsequent functionalization via hydrosilylation yielded Si NPs with an emission quantum yield of 12-14%. This approach can be used to easily produce high-quality H-Si NPs in gram-scale quantities, which brings the application of functionalized Si NPs significantly closer |
|---|---|
| Beschreibung: | Date Revised 28.12.2019 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 0897-4756 |
| DOI: | 10.1021/acs.chemmater.8b03113 |