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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201803366
|2 doi
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|a pubmed24n0962.xml
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|a (DE-627)NLM288755529
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|a (NLM)30239044
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Radhakrishnan, Sruthi
|e verfasserin
|4 aut
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|a An Insight into the Phase Transformation of WS2 upon Fluorination
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 05.11.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The transformation from semiconducting to metallic phase, accompanied by a structural transition in 2D transition metal dichalcogenides has attracted the attention of the researchers worldwide. The unconventional structural transformation of fluorinated WS2 (FWS2 ) into the 1T phase is described. The energy difference between the two phases debugs this transition, as fluorination enhances the stability of 1T FWS2 and makes it energetically favorable at higher F concentration. Investigation of the electronic and optical nature of FWS2 is supplemented by possible band structures and bandgap calculations. Magnetic centers in the 1T phase appear in FWS2 possibly due to the introduction of defect sites. A direct consequence of the phase transition and associated increase in interlayer spacing is a change in friction behavior. Friction force microscopy is used to determine this effect of functionalization accompanied phase transformation
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|a Journal Article
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|a 2D magnetism
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|a DFT calculations
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|a TMDs
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|a fluorination
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|a phase transformation
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|a Das, Deya
|e verfasserin
|4 aut
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|a Deng, Liangzi
|e verfasserin
|4 aut
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|a Sudeep, Parambath M
|e verfasserin
|4 aut
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|a Colas, Guillaume
|e verfasserin
|4 aut
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|a de Los Reyes, Carlos A
|e verfasserin
|4 aut
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1 |
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|a Yazdi, Sadegh
|e verfasserin
|4 aut
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1 |
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|a Chu, Ching Wu
|e verfasserin
|4 aut
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|a Martí, Angel A
|e verfasserin
|4 aut
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1 |
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|a Tiwary, Chandra Sekhar
|e verfasserin
|4 aut
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| 700 |
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|a Filleter, Tobin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Singh, Abhishek K
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ajayan, Pulickel M
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 44 vom: 12. Nov., Seite e1803366
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:30
|g year:2018
|g number:44
|g day:12
|g month:11
|g pages:e1803366
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|u http://dx.doi.org/10.1002/adma.201803366
|3 Volltext
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