|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM288448073 |
| 003 |
DE-627 |
| 005 |
20231225060328.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2018 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201804333
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0961.xml
|
| 035 |
|
|
|a (DE-627)NLM288448073
|
| 035 |
|
|
|a (NLM)30207621
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Chen, Gao
|e verfasserin
|4 aut
|
| 245 |
1 |
2 |
|a A Universal Strategy to Design Superior Water-Splitting Electrocatalysts Based on Fast In Situ Reconstruction of Amorphous Nanofilm Precursors
|
| 264 |
|
1 |
|c 2018
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 29.10.2018
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a The development of efficient bifunctional electrodes with extraordinary mass activity and robust stability is an eternal yet challenging goal for the water-splitting process. Surface reconstruction during electrocatalysis can form fresh-composition electrocatalysts with unusual amorphous phases in situ, which are more active but difficult to prepare by conventional methods. Here, a facile strategy based on fast reconstruction of amorphous nanofilm precursors is proposed for exploring precious-metal-free catalysts with good electronic conductivity, ultrahigh activity, and robust stability. As a proof of concept, an amorphous SrCo0.85 Fe0.1 P0.05 O3- δ (SCFP) nanofilm precursor with weak chemical bonds deposited onto a conductive nickel foam (NF) substrate (SCFP-NF) is synthesized by utilizing a high-energy argon plasma to break the strong chemical bonds in a crystalline SCFP target. The quickly reconstructed SCFP-NF bifunctional catalysts show ultrahigh mass activity of up to 1000 mA mg-1 at an overpotential of 550 mV and extremely long operational stability of up to 650 h at 10 mA cm-2 , significantly overperforming state-of-the-art precious-metal catalysts. Such a strategy is further demonstrated to be a universal method, which can be applied to accelerate the reconstruction of other material systems to obtain various efficient electrocatalysts
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a perovskites
|
| 650 |
|
4 |
|a plasma
|
| 650 |
|
4 |
|a surface reconstruction
|
| 650 |
|
4 |
|a water splitting
|
| 700 |
1 |
|
|a Hu, Zhiwei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhu, Yanping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gu, Binbin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhong, Yijun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lin, Hong-Ji
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Chien-Te
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhou, Wei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shao, Zongping
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 43 vom: 30. Okt., Seite e1804333
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2018
|g number:43
|g day:30
|g month:10
|g pages:e1804333
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201804333
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2018
|e 43
|b 30
|c 10
|h e1804333
|