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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.8b01694
|2 doi
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|a DE-627
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|a eng
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|a Yamamoto, Shunsuke
|e verfasserin
|4 aut
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|a High-Density and Monolayer-Level Integration of π-Conjugated Units
|b Amphiphilic Carbazole Homopolymer Langmuir-Blodgett Films
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|c 2018
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|a Text
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|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 07.11.2018
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|a Date Revised 07.11.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Precise integration of π-conjugated units is a key issue to achieve molecular (nano) electronic devices based on organic semiconductor materials. We specifically examine the Langmuir-Blodgett technique, which allows high-density integration of π-conjugated units. In this study, we designed a carbazole containing acrylamide-based homopolymer [poly(9-ethyl-3-carbazolyl acrylamide) (pCzAA)], in which the π-conjugated unit is connected with a hydrophilic amide unit directly as a side chain. Its Langmuir-Blodgett film formation properties were investigated. The pCzAA polymer took a stable monolayer formation in the presence of a small amount (ca. 10 mol %) of poly( N-dodecylacrylamide) (pDDA). Compared with amphiphilic carbazole-containing copolymers described in earlier reports, the direct connection of π-conjugated units through amide bonding enables the Cz content in monolayers to exceed that of the copolymer monolayers (ca. 30 mol %) dramatically. pCzAA:pDDA takes highly ordered layer structures toward the out-of-plane direction, although no structural order is formed in the in-plane direction. This method is a practical means to develop low-dimensional and high-density integration of π-conjugated units for molecular electronics
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Nishina, Nanae
|e verfasserin
|4 aut
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|a Matsui, Jun
|e verfasserin
|4 aut
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|a Miyashita, Tokuji
|e verfasserin
|4 aut
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|a Mitsuishi, Masaya
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 34(2018), 36 vom: 11. Sept., Seite 10491-10497
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:34
|g year:2018
|g number:36
|g day:11
|g month:09
|g pages:10491-10497
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|u http://dx.doi.org/10.1021/acs.langmuir.8b01694
|3 Volltext
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