Contactless Control of Local Surface Buckling in Photoaligned Gold/Liquid Crystal Polymer Bilayers

Wrinkling is a powerful technique for the preparation of surface structures over large areas, but it is difficult to simultaneously control the direction, period, and amplitude of the wrinkles without resorting to complicated procedures. In this work, we demonstrate a wrinkling system consisting of...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 36 vom: 11. Sept., Seite 10543-10549
1. Verfasser: de Haan, Laurens T (VerfasserIn)
Weitere Verfasser: Willigers, Timo J J, Wijkhuijs, Levina E A, Hendrikx, Matthew, Nguyen, Cuong Thai, Leclère, Philippe, Souren, Anne E J, Zhou, Guofu, Debije, Michael G
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
LEADER 01000naa a22002652 4500
001 NLM28728543X
003 DE-627
005 20231225053653.0
007 cr uuu---uuuuu
008 231225s2018 xx |||||o 00| ||eng c
024 7 |a 10.1021/acs.langmuir.8b01934  |2 doi 
028 5 2 |a pubmed24n0957.xml 
035 |a (DE-627)NLM28728543X 
035 |a (NLM)30089356 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a de Haan, Laurens T  |e verfasserin  |4 aut 
245 1 0 |a Contactless Control of Local Surface Buckling in Photoaligned Gold/Liquid Crystal Polymer Bilayers 
264 1 |c 2018 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 07.11.2018 
500 |a Date Revised 28.09.2023 
500 |a published: Print-Electronic 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a Wrinkling is a powerful technique for the preparation of surface structures over large areas, but it is difficult to simultaneously control the direction, period, and amplitude of the wrinkles without resorting to complicated procedures. In this work, we demonstrate a wrinkling system consisting of a liquid crystal polymer network and a thin layer of gold, in which the direction of the wrinkles is controlled by the alignment of the liquid crystal molecules and the average amplitude and period are controlled by a high-intensity UV irradiation. The UV exposure represses the amplitude and period dictated by the total exposure. Using photoalignment and photomasks, we demonstrate an unprecedented control over the wrinkling parameters and were able to generate some striking optical patterns. The mechanism of the wrinkle suppression was investigated and appears to involve localized photodegradation at the polymer-gold interface, possibly due to the formation of mechanoradicals 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
700 1 |a Willigers, Timo J J  |e verfasserin  |4 aut 
700 1 |a Wijkhuijs, Levina E A  |e verfasserin  |4 aut 
700 1 |a Hendrikx, Matthew  |e verfasserin  |4 aut 
700 1 |a Nguyen, Cuong Thai  |e verfasserin  |4 aut 
700 1 |a Leclère, Philippe  |e verfasserin  |4 aut 
700 1 |a Souren, Anne E J  |e verfasserin  |4 aut 
700 1 |a Zhou, Guofu  |e verfasserin  |4 aut 
700 1 |a Debije, Michael G  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1992  |g 34(2018), 36 vom: 11. Sept., Seite 10543-10549  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnns 
773 1 8 |g volume:34  |g year:2018  |g number:36  |g day:11  |g month:09  |g pages:10543-10549 
856 4 0 |u http://dx.doi.org/10.1021/acs.langmuir.8b01934  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 34  |j 2018  |e 36  |b 11  |c 09  |h 10543-10549