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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201705711
|2 doi
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|a pubmed24n1308.xml
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|a (NLM)30059171
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Liao, Kaiming
|e verfasserin
|4 aut
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|a Developing a "Water-Defendable" and "Dendrite-Free" Lithium-Metal Anode Using a Simple and Promising GeCl4 Pretreatment Method
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 27.02.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Lithium metal is an ultimate anode in "next-generation" rechargeable batteries, such as Li-sulfur batteries and Li-air (Li-O2 ) batteries. However, uncontrollable dendritic Li growth and water attack have prevented its practical applications, especially for open-system Li-O2 batteries. Here, it is reported that the issues can be addressed via the facile process of immersing the Li metal in organic GeCl4 -THF steam for several minutes before battery assembly. This creates a 1.5 µm thick protection layer composed of Ge, GeOx , Li2 CO3 , LiOH, LiCl, and Li2 O on Li surface that allows stable cycling of Li electrodes both in Li-symmetrical cells and Li-O2 cells, especially in "moist" electrolytes (with 1000-10 000 ppm H2 O) and humid O2 atmosphere (relative humidity (RH) of 45%). This work illustrates a simple and effective way for the unfettered development of Li-metal-based batteries
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|a Journal Article
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4 |
|a Li pretreatment
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|a Li-O2 battery
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|a humid oxygen
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4 |
|a moist electrolyte
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1 |
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|a Wu, Shichao
|e verfasserin
|4 aut
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1 |
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|a Mu, Xiaowei
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lu, Qian
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Han, Min
|e verfasserin
|4 aut
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| 700 |
1 |
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|a He, Ping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Shao, Zongping
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhou, Haoshen
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2018) vom: 30. Juli, Seite e1705711
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g year:2018
|g day:30
|g month:07
|g pages:e1705711
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|u http://dx.doi.org/10.1002/adma.201705711
|3 Volltext
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|j 2018
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