|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM286807173 |
| 003 |
DE-627 |
| 005 |
20231225052603.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2018 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.8b01734
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0956.xml
|
| 035 |
|
|
|a (DE-627)NLM286807173
|
| 035 |
|
|
|a (NLM)30040426
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Aitchison, Hannah
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Self-Assembly of Di(pyrazol-1-yl)pyridine-benzoic Acid on Underpotentially Deposited Ag from Solution
|
| 264 |
|
1 |
|c 2018
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 17.10.2018
|
| 500 |
|
|
|a Date Revised 17.10.2018
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Monolayers of 4-(2,6-di(1 H-pyrazol-1-yl)pyridine-4-yl)benzoic acid (DPP-BA) on Au substrates modified by an underpotential-deposited bilayer of Ag were studied by X-ray photoelectron spectroscopy (XPS), near edge X-ray absorption fine structure spectroscopy, and scanning tunneling microscopy. Highly crystalline layers are formed with molecules coordinatively bonding to the surface through the carboxylate moiety in a bidentate configuration. The molecules assemble to rows characterized by densely packed upright-orientated DPP units occupying an area of 41 Å2. The DPP units adopt a trans-trans conformation as inferred from the N 1s XPS spectra taken at different photon energies. Their alignment alternates between adjacent rows, giving rise to a herringbone pattern. The pronouncedly different structure of the weakly commensurate self-assembled monolayer (SAM) of DPP-BA on Ag compared to the commensurate SAM of a DPP thiol on Au is a manifestation of the shift from substrate-directed assembly in the latter case to assembly dominated by intermolecular interactions in the former case
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 700 |
1 |
|
|a Ortiz de la Morena, Rodrigo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Peifer, Raphael
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Omar, Suhad
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lu, Hao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Francis, Stephen M
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zharnikov, Michael
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Grohmann, Andreas
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Buck, Manfred
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 34(2018), 33 vom: 21. Aug., Seite 9654-9664
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:34
|g year:2018
|g number:33
|g day:21
|g month:08
|g pages:9654-9664
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.8b01734
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 34
|j 2018
|e 33
|b 21
|c 08
|h 9654-9664
|