Hollow Metal Nanocrystals with Ultrathin, Porous Walls and Well-Controlled Surface Structures
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 30(2018), 48 vom: 08. Nov., Seite e1801956 |
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| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2018
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article Review catalysts fuel cells hollow nanocrystals nanocages oxygen reduction reaction |
| Zusammenfassung: | © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Recent developments of a novel class of catalytic materials built on hollow nanocrystals having ultrathin, porous walls, and well-controlled surface structures are discussed, with a focus on platinum and the oxygen reduction reaction (ORR). An introduction is given to the critical role of platinum in the proton exchange membrane fuel cells, and the pressing need to develop a strategy for achieving cost-effective and sustainable use of this precious metal. How to maximize the mass activity of ORR catalysts based on platinum by rationally engineering the surface structure while increasing the utilization efficiency of atoms is then discussed. After reporting on the synthetic methods involving galvanic replacement and seed-mediated growth followed by etching, respectively, a number of examples to demonstrate the enhancement in activity and durability for this new class of catalytic materials are showcased. The feasibility to have the methodology extended from platinum to other precious metals such as gold and ruthenium is highlighted. In conclusion, some of the remaining issues and emerging solutions are examined |
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| Beschreibung: | Date Completed 11.12.2018 Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201801956 |