Cold Sintered Ceramic Nanocomposites of 2D MXene and Zinc Oxide

© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 30(2018), 32 vom: 26. Aug., Seite e1801846
1. Verfasser: Guo, Jing (VerfasserIn)
Weitere Verfasser: Legum, Benjamin, Anasori, Babak, Wang, Ke, Lelyukh, Pavel, Gogotsi, Yury, Randall, Clive A
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D MXene ZnO low temperature sintering nanocomposite thermoelectric
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520 |a Nanocomposites containing 2D materials have attracted much attention due to their potential for enhancing electrical, magnetic, optical, mechanical, and thermal properties. However, it has been a challenge to integrate 2D materials into ceramic matrices due to interdiffusion and chemical reactions at high temperatures. A recently reported sintering technique, the cold sintering process (CSP), which densifies ceramics with the assistance of transient aqueous solutions, provides a means to circumvent the aforementioned problems. The efficacious co-sintering of Ti3 C2 Tx (MXene), a 2D transition carbide, with ZnO, an oxide matrix, is reported. Using CSP, the ZnO-Ti3 C2 Tx nanocomposites can be sintered to 92-98% of the theoretical density at 300 °C, while avoiding oxidation or interdiffusion and showing homogeneous distribution of the 2D materials along the ZnO grain boundaries. The electrical conductivity is improved by 1-2 orders of magnitude due to the addition of up to 5 wt% MXene. The hardness and elastic modulus show an increase of 40-50% with 0.5 wt% MXene, and over 150% with 5 wt% of MXene. The successful densification of ZnO-MXene nanocomposite demonstrates that the cold sintering of ceramics with 2D materials is a promising processing route for designing new nanocomposites with a diverse range of applications 
650 4 |a Journal Article 
650 4 |a 2D 
650 4 |a MXene 
650 4 |a ZnO 
650 4 |a low temperature sintering 
650 4 |a nanocomposite 
650 4 |a thermoelectric 
700 1 |a Legum, Benjamin  |e verfasserin  |4 aut 
700 1 |a Anasori, Babak  |e verfasserin  |4 aut 
700 1 |a Wang, Ke  |e verfasserin  |4 aut 
700 1 |a Lelyukh, Pavel  |e verfasserin  |4 aut 
700 1 |a Gogotsi, Yury  |e verfasserin  |4 aut 
700 1 |a Randall, Clive A  |e verfasserin  |4 aut 
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