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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/ejic.201800168
|2 doi
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|a eng
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| 100 |
1 |
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|a Jongbloed, Linda S
|e verfasserin
|4 aut
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|a Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 26.09.2023
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Based on previous work related to the design and application of rigid tridentate phosphine-pyridine-phenyl coordination offered by a PNC-pincer ligand upon cyclometalation to nickel, the synthesis, spectroscopic and solid state characterization and redox-reactivity of two NiII(PNC) complexes featuring either a methyl (2CH3 ) or CF3 co-ligand (2CF3 ) are described. One-electron oxidation is proposed to furnish C-C reductive elimination, as deduced from a combined chemical, electrochemical, spectroscopic and computational study. One-electron reduction results in a ligand-centered radical anion, as supported by electrochemistry, UV spectroelectrochemistry, EPR spectroscopy, and DFT calculations. This further attenuates the breadth of chemical reactivity offered by such PNC-pincer ligands
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|a Journal Article
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|a C–C reductive elimination
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|a Nickel
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|a Pincer ligands
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|a Radical ions
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| 650 |
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|a Redox chemistry
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1 |
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|a Vogt, Nicolas
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sandleben, Aaron
|e verfasserin
|4 aut
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| 700 |
1 |
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|a de Bruin, Bas
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Klein, Axel
|e verfasserin
|4 aut
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|a van der Vlugt, Jarl Ivar
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t European journal of inorganic chemistry
|d 1998
|g 2018(2018), 20-21 vom: 07. Juni, Seite 2408-2418
|w (DE-627)NLM098272756
|x 1434-1948
|7 nnns
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| 773 |
1 |
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|g volume:2018
|g year:2018
|g number:20-21
|g day:07
|g month:06
|g pages:2408-2418
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| 856 |
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|u http://dx.doi.org/10.1002/ejic.201800168
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