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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201800400
|2 doi
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|a pubmed24n0947.xml
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|a eng
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1 |
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|a Xiao, Kefeng
|e verfasserin
|4 aut
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|a A 2D Conductive Organic-Inorganic Hybrid with Extraordinary Volumetric Capacitance at Minimal Swelling
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 01.08.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Rational design and synthesis of 2D organic-inorganic hybrid materials is important for transformative technological advances for energy storage. Here, a 2D conductive hybrid lamella and its intercalation properties for thin-film supercapacitors are reported. The 2D organic-inorganic hybrid lamella comprises periodically stacked 2D nanosheets with 11.81 Å basal spacing, and is electronically conductive (605 S m-1 ). In contrast to the pre-existing organic-based 2D materials, this material has extremely low gas-permeable porosity (16.5 m2 g-1 ) in contrast to the high ionic accessibility. All these structural features collectively contribute to the high capacitances up to 732 F cm-3 , combined with small structural swelling at as low as 4.8% and good stability. At a discharge time of 6 s, the thin-film intercalation electrode delivers an energy density of 24 mWh cm-3 , which universally outperforms the surface-dominant capacitive processes in porous carbons
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|a Journal Article
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|a 2D materials
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|a intercalation electrodes
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|a organic-inorganic hybrid materials
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|a supercapacitors
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|a volumetric performance
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|a Jiang, Donglin
|e verfasserin
|4 aut
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|a Amal, Rose
|e verfasserin
|4 aut
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| 700 |
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|a Wang, Da-Wei
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 26 vom: 11. Juni, Seite e1800400
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:30
|g year:2018
|g number:26
|g day:11
|g month:06
|g pages:e1800400
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|u http://dx.doi.org/10.1002/adma.201800400
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