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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201800159
|2 doi
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|a pubmed24n0945.xml
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|a eng
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| 100 |
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|a Wales, Dominic J
|e verfasserin
|4 aut
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|a 3D-Printable Photochromic Molecular Materials for Reversible Information Storage
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|c 2018
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 01.08.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The formulation of advanced molecular materials with bespoke polymeric ionic-liquid matrices that stabilize and solubilize hybrid organic-inorganic polyoxometalates and allow their processing by additive manufacturing, is effectively demonstrated. The unique photo and redox properties of nanostructured polyoxometalates are translated across the scales (from molecular design to functional materials) to yield macroscopic functional devices with reversible photochromism. These properties open a range of potential applications including reversible information storage based on controlled topological and temporal reduction/oxidation of pre-formed printed devices. This approach pushes the boundaries of 3D printing to the molecular limits, allowing the freedom of design enabled by 3D printing to be coupled with the molecular tuneability of polymerizable ionic liquids and the photoactivity and orbital engineering possible with hybrid polyoxometalates
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|a Journal Article
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|a 3D printing
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|a photochromism
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|a poly(ionic liquids)
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|a polyoxometalates
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|a smart materials
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|a Cao, Qun
|e verfasserin
|4 aut
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1 |
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|a Kastner, Katharina
|e verfasserin
|4 aut
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1 |
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|a Karjalainen, Erno
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Newton, Graham N
|e verfasserin
|4 aut
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|a Sans, Victor
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 26 vom: 11. Juni, Seite e1800159
|w (DE-627)NLM098206397
|x 1521-4095
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|g volume:30
|g year:2018
|g number:26
|g day:11
|g month:06
|g pages:e1800159
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|u http://dx.doi.org/10.1002/adma.201800159
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