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231225s2018 xx |||||o 00| ||eng c |
| 024 |
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|a 10.1021/acs.langmuir.8b00649
|2 doi
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| 028 |
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2 |
|a pubmed24n0943.xml
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|a DE-627
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|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Yanagi, Kanta
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Polyrotaxane Brushes Dynamically Formed at a Water/Elastomer Interface
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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| 500 |
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|a Date Completed 10.09.2018
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|a Date Revised 10.09.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Dense polymer brushes with closely packed rotaxane structures were formed at the interface of water and a styrene-butadiene elastomer by spontaneous segregation of an amphiphilic polyrotaxane (PR), a mechanically interlocked polymer consisting of hydrophobic polybutadiene threading through multiple hydrophilic γ-cyclodextrin (γ-CD) derivatives. Segregation of PR at the water/elastomer interface was suggested by X-ray photoelectron spectroscopy. The polymer brush structure at the water interface was investigated using neutron reflectometry. Brush structures were found to depend on the number of CDs on the PRs; the PR with a small number of CDs formed a thinner and homogeneous brush, whereas the PR with a higher number of CDs formed a thicker and less-ordered brush. These PR-brushes showed protein repulsion, resulting from the surface-hydrated brush layer preventing direct contact of proteins
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|a Journal Article
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| 650 |
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|a Research Support, Non-U.S. Gov't
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| 700 |
1 |
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|a Yamada, Norifumi L
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kato, Kazuaki
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ito, Kohzo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yokoyama, Hideaki
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 34(2018), 18 vom: 08. Mai, Seite 5297-5302
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
8 |
|g volume:34
|g year:2018
|g number:18
|g day:08
|g month:05
|g pages:5297-5302
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| 856 |
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|u http://dx.doi.org/10.1021/acs.langmuir.8b00649
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