|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM282606475 |
| 003 |
DE-627 |
| 005 |
20231225034322.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2018 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201706317
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0942.xml
|
| 035 |
|
|
|a (DE-627)NLM282606475
|
| 035 |
|
|
|a (NLM)29611231
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Liu, Dai-Huo
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a In Situ Encapsulating α-MnS into N,S-Codoped Nanotube-Like Carbon as Advanced Anode Material
|b α → β Phase Transition Promoted Cycling Stability and Superior Li/Na-Storage Performance in Half/Full Cells
|
| 264 |
|
1 |
|c 2018
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 06.08.2018
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Incorporation of N,S-codoped nanotube-like carbon (N,S-NTC) can endow electrode materials with superior electrochemical properties owing to the unique nanoarchitecture and improved kinetics. Herein, α-MnS nanoparticles (NPs) are in situ encapsulated into N,S-NTC, preparing an advanced anode material (α-MnSN,S-NTC) for lithium-ion/sodium-ion batteries (LIBs/SIBs). It is for the first time revealed that electrochemical α → β phase transition of MnS NPs during the 1st cycle effectively promotes Li-storage properties, which is deduced by the studies of ex situ X-ray diffraction/high-resolution transmission electron microscopy and electrode kinetics. As a result, the optimized α-MnS@N,S-NTC electrode delivers a high Li-storage capacity (1415 mA h g-1 at 50 mA g-1 ), excellent rate capability (430 mA h g-1 at 10 A g-1 ), and long-term cycling stability (no obvious capacity decay over 5000 cycles at 1 A g-1 ) with retained morphology. In addition, the N,S-NTC-based encapsulation plays the key roles on enhancing the electrochemical properties due to its high conductivity and unique 1D nanoarchitecture with excellent protective effects to active MnS NPs. Furthermore, α-MnS@N,S-NTC also delivers high Na-storage capacity (536 mA h g-1 at 50 mA g-1 ) without the occurrence of such α → β phase transition and excellent full-cell performances as coupling with commercial LiFePO4 and LiNi0.6 Co0.2 Mn0.2 O2 cathodes in LIBs as well as Na3 V2 (PO4 )2 O2 F cathode in SIBs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Li/Na storage
|
| 650 |
|
4 |
|a N,S-codoped carbon
|
| 650 |
|
4 |
|a phase transition
|
| 650 |
|
4 |
|a α-MnS
|
| 650 |
|
4 |
|a β-MnS
|
| 700 |
1 |
|
|a Li, Wen-Hao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zheng, Yan-Ping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Cui, Zheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Xin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Dao-Sheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Jiawei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Yu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lü, Hong-Yan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Bai, Feng-Yang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Jin-Zhi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Xing-Long
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 21 vom: 02. Mai, Seite e1706317
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2018
|g number:21
|g day:02
|g month:05
|g pages:e1706317
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201706317
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2018
|e 21
|b 02
|c 05
|h e1706317
|