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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.7b04337
|2 doi
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|a pubmed24n0940.xml
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|a eng
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| 100 |
1 |
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|a Kataoka, Sho
|e verfasserin
|4 aut
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| 245 |
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|a Toward Increasing Micropore Volume between Hybrid Layered Perovskites with Silsesquioxane Interlayers
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 10.09.2018
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|a Date Revised 10.09.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Hybrid organic-inorganic layered perovskites are typically nonporous solids. However, the incorporation of silsesquioxanes with a cubic cage structure as interlayer materials creates micropores between the perovskite layers. In this study, we increase in the micropore volume in layered perovskites by replacing a portion of the silsesquioxane interlayers with organic amines. In the proposed method, approximately 20% of the silsesquioxane interlayers can be replaced without changing the layer distance owing to the size of the silsesquioxane. When small amines (e.g., ethylamine) are used in this manner, the micropore volume of the obtained hybrid layered perovskites increases by as much as 44%; when large amines (e.g., phenethylamine) are used, their micropore volume decreases by as much as 43%. Through the variation of amine fraction, the micropore volume can be adjusted in the range. Finally, the magnetic moment measurements reveal that the layered perovskites with mixed interlayers exhibit ferromagnetic ordering at temperature below 20 K, thus indicating that the obtained perovskites maintain their functions as layered perovskites
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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1 |
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|a Kamimura, Yoshihiro
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Endo, Akira
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 34(2018), 14 vom: 10. Apr., Seite 4166-4172
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|x 1520-5827
|7 nnns
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|g volume:34
|g year:2018
|g number:14
|g day:10
|g month:04
|g pages:4166-4172
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|u http://dx.doi.org/10.1021/acs.langmuir.7b04337
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