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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.8b00038
|2 doi
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|a pubmed24n0939.xml
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|a eng
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|a Brugman, Sander J T
|e verfasserin
|4 aut
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|a Concentration-Dependent Adsorption of CsI at the Muscovite-Electrolyte Interface
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|c 2018
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 06.07.2018
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|a Date Revised 14.11.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The interfacial structure of muscovite in contact with aqueous CsI solutions was measured using surface X-ray diffraction for several CsI concentrations (2-1000 mM). At CsI concentrations up to 200 mM, Cs+ adsorption is likely hindered by H3O+, as both cations compete for the adsorption site above the muscovite hexagonal cavity. Above this concentration, more Cs+ adsorbs than is required to compensate the negatively charged muscovite surface, which means that coadsorption of an anion takes place. The I- anion does not coadsorb in an ordered manner. Moreover, the hydration ring and water layers do not change significantly as a function of the CsI concentration
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|a Journal Article
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|a Townsend, Eleanor R
|e verfasserin
|4 aut
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|a Smets, Mireille M H
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Accordini, Paolo
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Vlieg, Elias
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 34(2018), 13 vom: 03. Apr., Seite 3821-3826
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:34
|g year:2018
|g number:13
|g day:03
|g month:04
|g pages:3821-3826
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|u http://dx.doi.org/10.1021/acs.langmuir.8b00038
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