Impact of Polyelectrolyte Multilayers on the Ionic Current Rectification of Conical Nanopores

Single conical nanopores were functionalised layer by layer with weak polyelectrolytes. We studied their influence on the ionic diode properties We have considered different couples of polyelectrolytes: poly-l-lysine/poly(acrylic acid) and poly(ethyleneimine)/poly(acrylic acid) as well as the influe...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 11 vom: 20. März, Seite 3405-3412
1. Verfasser: Ma, Tianji (VerfasserIn)
Weitere Verfasser: Gaigalas, Paulius, Lepoitevin, Mathilde, Plikusiene, Ieva, Bechelany, Mikhael, Janot, Jean-Marc, Balanzat, Emmanuel, Balme, Sebastien
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a Single conical nanopores were functionalised layer by layer with weak polyelectrolytes. We studied their influence on the ionic diode properties We have considered different couples of polyelectrolytes: poly-l-lysine/poly(acrylic acid) and poly(ethyleneimine)/poly(acrylic acid) as well as the influence of cross-linking. The results show that the nanopores decorated with poly(ethyleneimine)/poly(acrylic acid) exhibit an interesting behavior. Indeed, at pH 3, the nanopore is open only at the low salt concentration, while at pH 7, it is already open. The nanopores functionalized with poly-l-lysine/poly(acrylic acid) do not show an inversion of ionic transport properties with the pH as expected. After cross-linked to prevent large conformational changes, the ionic diode properties are dependent on the pH 
650 4 |a Journal Article 
700 1 |a Gaigalas, Paulius  |e verfasserin  |4 aut 
700 1 |a Lepoitevin, Mathilde  |e verfasserin  |4 aut 
700 1 |a Plikusiene, Ieva  |e verfasserin  |4 aut 
700 1 |a Bechelany, Mikhael  |e verfasserin  |4 aut 
700 1 |a Janot, Jean-Marc  |e verfasserin  |4 aut 
700 1 |a Balanzat, Emmanuel  |e verfasserin  |4 aut 
700 1 |a Balme, Sebastien  |e verfasserin  |4 aut 
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