Combined treatment of hydroxypropyl guar gum in oilfield fracturing wastewater by coagulation and the UV/H2O2/ferrioxalate complexes process

Hydroxypropyl guar gum is considered to be a main component of oilfield fracturing wastewater (OFW). This work is intended to optimize the experimental conditions for the maximum oxidative degradation of hydroxypropyl guar gum by the coagulation and UV/H2O2/ferrioxalate complexes process. Optimal re...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 77(2018), 3-4 vom: 29. Feb., Seite 565-575
1. Verfasser: Zhang, Zhenchao (VerfasserIn)
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Acrylic Resins Industrial Waste Oxalates Polysaccharides Waste Water Water Pollutants, Chemical hydroxypropyl guar ferrioxalate 15321-61-6 mehr... polyacrylamide 9003-05-8 Hydrogen Peroxide BBX060AN9V
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245 1 0 |a Combined treatment of hydroxypropyl guar gum in oilfield fracturing wastewater by coagulation and the UV/H2O2/ferrioxalate complexes process 
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520 |a Hydroxypropyl guar gum is considered to be a main component of oilfield fracturing wastewater (OFW). This work is intended to optimize the experimental conditions for the maximum oxidative degradation of hydroxypropyl guar gum by the coagulation and UV/H2O2/ferrioxalate complexes process. Optimal reaction conditions were proposed based on the chemical oxygen demand (COD) removal efficiency and UV_vis spectra analysis. The overall removal efficiency of COD reached 83.8% for a dilution ratio of raw wastewater of 1:2, pH of 4 and FeCl3 loading of 1,000 mg/L in the coagulation process; the dosage of H2O2 (30%,v/v) was 0.6% (v/v) and added in three steps, the n(H2O2)/n(Fe2+) was 2:1, n(Fe2+)/n(C2O42-) was 3:1 and pH was 4 in the UV/H2O2/ferrioxalate complexes process; pH was adjusted to 8.5-9 by NaOH and then cationic polyacrylamide (CPAM) of 2 mg/L was added in the neutralization and flocculation process. The decrease in COD during the coagulation process reduced the required H2O2 dosage and improved efficiency in the subsequent UV/H2O2/ferrioxalate complexes process. Furthermore, COD removal efficiency significantly increased by more than 13.4% with the introduction of oxalate compared with UV/Fenton. The UV_vis spectra analysis results indicated that the coagulation and UV/H2O2/ferrioxalate complexes process could efficiently remove the hydroxypropyl guar gum dissolved in OFW. An optimal combination of these parameters produced treated wastewater that met the GB8978-1996 Integrated Wastewater Discharge Standard level III emission standard 
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650 7 |a Industrial Waste  |2 NLM 
650 7 |a Oxalates  |2 NLM 
650 7 |a Polysaccharides  |2 NLM 
650 7 |a Waste Water  |2 NLM 
650 7 |a Water Pollutants, Chemical  |2 NLM 
650 7 |a hydroxypropyl guar  |2 NLM 
650 7 |a ferrioxalate  |2 NLM 
650 7 |a 15321-61-6  |2 NLM 
650 7 |a polyacrylamide  |2 NLM 
650 7 |a 9003-05-8  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
650 7 |a BBX060AN9V  |2 NLM 
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773 1 8 |g volume:77  |g year:2018  |g number:3-4  |g day:29  |g month:02  |g pages:565-575 
856 4 0 |u http://dx.doi.org/10.2166/wst.2017.552  |3 Volltext 
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