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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201704501
|2 doi
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|a pubmed24n0934.xml
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|a eng
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1 |
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|a Dissegna, Stefano
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Defective Metal-Organic Frameworks
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|c 2018
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 11.09.2018
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The targeted incorporation of defects into crystalline matter allows for the manipulation of many properties and has led to relevant discoveries for optimized and even novel technological applications of materials. It is therefore exciting to see that defects are now recognized to be similarly useful in tailoring properties of metal-organic frameworks (MOFs). For instance, heterogeneous catalysis crucially depends on the number of active catalytic sites as well as on diffusion limitations. By the incorporation of missing linker and missing node defects into MOFs, both parameters can be accessed, improving the catalytic properties. Furthermore, the creation of defects allows for adding properties such as electronic conductivity, which are inherently absent in the parent MOFs. Herein, progress of the rapidly evolving field of the past two years is overviewed, putting a focus on properties that are altered by the incorporation and even tailoring of defects in MOFs. A brief account is also given on the emerging quantitative understanding of defects and heterogeneity in MOFs based on scale-bridging computational modeling and simulations
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|a Journal Article
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|a Review
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|a catalysis
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|a defects
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|a electrical conductivity
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|a metal-organic frameworks
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|a sorption
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|a Epp, Konstantin
|e verfasserin
|4 aut
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|a Heinz, Werner R
|e verfasserin
|4 aut
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|a Kieslich, Gregor
|e verfasserin
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|a Fischer, Roland A
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 37 vom: 24. Sept., Seite e1704501
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:30
|g year:2018
|g number:37
|g day:24
|g month:09
|g pages:e1704501
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|u http://dx.doi.org/10.1002/adma.201704501
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