Wisely Designed Phthalocyanine Derivative for Convenient Molecular Fabrication on a Substrate

An axial-substituted silicon phthalocyanine derivative, SiPc(OR)2 (R = C4H9), that is soluble in organic solvent is conveniently synthesized. This silicon phthalocyanine derivative reacts with a hydroxyl group on a substrate and then with another phthalocyanine derivative under mild conditions. The...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 34(2018), 4 vom: 30. Jan., Seite 1321-1326
1. Verfasser: Harada, Wataru (VerfasserIn)
Weitere Verfasser: Hirahara, Mana, Togashi, Takanari, Ishizaki, Manabu, Kurihara, Masato, Haga, Masa-Aki, Kanaizuka, Katsuhiko
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2018
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Indoles Organosilicon Compounds Photosensitizing Agents silicon phthalocyanine 135719-28-7
Beschreibung
Zusammenfassung:An axial-substituted silicon phthalocyanine derivative, SiPc(OR)2 (R = C4H9), that is soluble in organic solvent is conveniently synthesized. This silicon phthalocyanine derivative reacts with a hydroxyl group on a substrate and then with another phthalocyanine derivative under mild conditions. The accumulation number of the phthalocyanine molecules on the substrates is easily controlled by the immersion time. On the basis of AFM (atomic force microscopy) images, the surface of the phthalocyanine-modified glass substrate has uneven structures on the nanometer scale. ITO electrodes modified with the composition of the phthalocyanine derivative and PCBM show stable cathodic photocurrent generation upon light irradiation
Beschreibung:Date Completed 17.09.2018
Date Revised 17.09.2018
published: Print-Electronic
Citation Status MEDLINE
ISSN:1520-5827
DOI:10.1021/acs.langmuir.7b03466