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231225s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201704681
|2 doi
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|a pubmed24n0930.xml
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|a (DE-627)NLM279041276
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|a (NLM)29239518
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Yin, Jie
|e verfasserin
|4 aut
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|a Oxygen Vacancies Dominated NiS2 /CoS2 Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 18.07.2018
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|a Date Revised 06.12.2021
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The development of highly active and stable oxygen evolution reaction (OER) electrocatalysts is crucial for improving the efficiency of water splitting and metal-air battery devices. Herein, an efficient strategy is demonstrated for making the oxygen vacancies dominated cobalt-nickel sulfide interface porous nanowires (NiS2 /CoS2 -O NWs) for boosting OER catalysis through in situ electrochemical reaction of NiS2 /CoS2 interface NWs. Because of the abundant oxygen vacancies and interface porous nanowires structure, they can catalyze the OER efficiently with a low overpotential of 235 mV at j = 10 mA cm-2 and remarkable long-term stability in 1.0 m KOH. The home-made rechargeable portable Zn-air batteries by using NiS2 /CoS2 -O NWs as the air-cathode display a very high open-circuit voltage of 1.49 V, which can maintain for more than 30 h. Most importantly, a highly efficient self-driven water splitting device is designed with NiS2 /CoS2 -O NWs as both anode and cathode, powered by two-series-connected NiS2 /CoS2 -O NWs-based portable Zn-air batteries. The present work opens a new way for designing oxygen vacancies dominated interface nanowires as highly efficient multifunctional electrocatalysts for electrochemical reactions and renewable energy devices
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|a Journal Article
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|a Zn-air batteries
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|a interface catalysis
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|a oxygen vacancies
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|a porous nanowires
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|a water splitting
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|a Li, Yuxuan
|e verfasserin
|4 aut
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|a Lv, Fan
|e verfasserin
|4 aut
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|a Lu, Min
|e verfasserin
|4 aut
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|a Sun, Ke
|e verfasserin
|4 aut
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|a Wang, Wei
|e verfasserin
|4 aut
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|a Wang, Lei
|e verfasserin
|4 aut
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|a Cheng, Fangyi
|e verfasserin
|4 aut
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|a Li, Yefei
|e verfasserin
|4 aut
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|a Xi, Pinxian
|e verfasserin
|4 aut
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|a Guo, Shaojun
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 47 vom: 19. Dez.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:29
|g year:2017
|g number:47
|g day:19
|g month:12
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|u http://dx.doi.org/10.1002/adma.201704681
|3 Volltext
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