Oxygen Vacancies Dominated NiS2 /CoS2 Interface Porous Nanowires for Portable Zn-Air Batteries Driven Water Splitting Devices

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 29(2017), 47 vom: 19. Dez.
1. Verfasser: Yin, Jie (VerfasserIn)
Weitere Verfasser: Li, Yuxuan, Lv, Fan, Lu, Min, Sun, Ke, Wang, Wei, Wang, Lei, Cheng, Fangyi, Li, Yefei, Xi, Pinxian, Guo, Shaojun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2017
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Zn-air batteries interface catalysis oxygen vacancies porous nanowires water splitting
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520 |a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 
520 |a The development of highly active and stable oxygen evolution reaction (OER) electrocatalysts is crucial for improving the efficiency of water splitting and metal-air battery devices. Herein, an efficient strategy is demonstrated for making the oxygen vacancies dominated cobalt-nickel sulfide interface porous nanowires (NiS2 /CoS2 -O NWs) for boosting OER catalysis through in situ electrochemical reaction of NiS2 /CoS2 interface NWs. Because of the abundant oxygen vacancies and interface porous nanowires structure, they can catalyze the OER efficiently with a low overpotential of 235 mV at j = 10 mA cm-2 and remarkable long-term stability in 1.0 m KOH. The home-made rechargeable portable Zn-air batteries by using NiS2 /CoS2 -O NWs as the air-cathode display a very high open-circuit voltage of 1.49 V, which can maintain for more than 30 h. Most importantly, a highly efficient self-driven water splitting device is designed with NiS2 /CoS2 -O NWs as both anode and cathode, powered by two-series-connected NiS2 /CoS2 -O NWs-based portable Zn-air batteries. The present work opens a new way for designing oxygen vacancies dominated interface nanowires as highly efficient multifunctional electrocatalysts for electrochemical reactions and renewable energy devices 
650 4 |a Journal Article 
650 4 |a Zn-air batteries 
650 4 |a interface catalysis 
650 4 |a oxygen vacancies 
650 4 |a porous nanowires 
650 4 |a water splitting 
700 1 |a Li, Yuxuan  |e verfasserin  |4 aut 
700 1 |a Lv, Fan  |e verfasserin  |4 aut 
700 1 |a Lu, Min  |e verfasserin  |4 aut 
700 1 |a Sun, Ke  |e verfasserin  |4 aut 
700 1 |a Wang, Wei  |e verfasserin  |4 aut 
700 1 |a Wang, Lei  |e verfasserin  |4 aut 
700 1 |a Cheng, Fangyi  |e verfasserin  |4 aut 
700 1 |a Li, Yefei  |e verfasserin  |4 aut 
700 1 |a Xi, Pinxian  |e verfasserin  |4 aut 
700 1 |a Guo, Shaojun  |e verfasserin  |4 aut 
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773 1 8 |g volume:29  |g year:2017  |g number:47  |g day:19  |g month:12 
856 4 0 |u http://dx.doi.org/10.1002/adma.201704681  |3 Volltext 
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