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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201704350
|2 doi
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|a pubmed24n0929.xml
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|a (NLM)29215175
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Mo, Zong-Wen
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Mesoporous Metal-Organic Frameworks with Exceptionally High Working Capacities for Adsorption Heat Transformation
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|c 2018
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 01.08.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Pore size is one of the most important parameters of adsorbents, and mesoporous materials have received intense attention for large guests. Here, a series of mesoporous coordination polymers underlying a new framework prototype for fast expansion of pore size is reported and the profound effect of pore size on adsorption heat transformation is demonstrated. Three isostructural honeycomb-like frameworks are designed and synthesized by combining ditopic linear metal oxalate chains and triangular tris-pyridine ligands. Changing the ligand bridging length from 5.5 to 8.6 and 9.9 Å gives rise to effective pore diameter from 20 to 33 and 37 Å, surface area from 2096 to 2630 and 2749 m2 g-1 , and pore volume from 1.19 to 1.93 and 2.36 cm3 g-1 , respectively. By virtue of the unique and tunable isotherm shape of mesopores, exceptionally large working capacity up to 1.19 g g-1 or 0.38 g cm-3 for adsorption heat transformation can be achieved using R-134a (1,1,1,2-tetrafluroethane) as a working fluid
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|a Journal Article
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|a R-134a adsorption refrigeration
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4 |
|a heat transformation
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|a metal-organic frameworks
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4 |
|a pore size
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1 |
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|a Zhou, Hao-Long
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhou, Dong-Dong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Lin, Rui-Biao
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liao, Pei-Qin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a He, Chun-Ting
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Wei-Xiong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Chen, Xiao-Ming
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Jie-Peng
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 4 vom: 01. Jan.
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|u http://dx.doi.org/10.1002/adma.201704350
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