|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM27844315X |
| 003 |
DE-627 |
| 005 |
20231225020611.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2018 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201705219
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0928.xml
|
| 035 |
|
|
|a (DE-627)NLM27844315X
|
| 035 |
|
|
|a (NLM)29178490
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Kong, Long
|e verfasserin
|4 aut
|
| 245 |
1 |
2 |
|a A Bifunctional Perovskite Promoter for Polysulfide Regulation toward Stable Lithium-Sulfur Batteries
|
| 264 |
|
1 |
|c 2018
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 01.08.2018
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Lithium-sulfur (LiS) batteries are strongly considered as the next-generation rechargeable cells. However, both the shuttle of lithium polysulfides (LiPSs) and sluggish kinetics in random deposition of lithium sulfides (Li2 S) significantly degrade the capacity, rate performance, and cycling life of LiS cells. Herein, bifunctional Ba0.5 Sr0.5 Co0.8 Fe0.2 O3-δ perovskite nanoparticles (PrNPs) are proposed as a promoter to immobilize LiPSs and guide the deposition of Li2 S in a LiS cell. The oxygen vacancy in PrNPs increases the metal reactivity to anchor LiPSs, and co-existence of lithiophilic (O) and sulfiphilic (Sr) sites in PrNP favor the dual-bonding (LiO and SrS bonds) to anchor LiPSs. The high catalytic nature of PrNP facilitates the kinetics of LiPS redox reaction. The PrNP with intrinsic LiPS affinity serves as nucleation sites for Li2 S deposition and guides its uniform propagation. Therefore, the bifunctional LiPS promoter in LiS cell yields high rate performance and ultralow capacity decay rate of 0.062% (a quarter of pristine LiS cells). The proposed strategy to immobilize LiPSs, promotes the conversion of LiPS, and regulates deposition of Li2 S by an emerging perovskite promoter and is also expected to be applied in other energy conversion and storage devices based on multi-electron redox reactions
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a bifunctional perovskite promoters
|
| 650 |
|
4 |
|a composite cathodes
|
| 650 |
|
4 |
|a lithium-sulfur batteries
|
| 650 |
|
4 |
|a polysulfide redox reactions
|
| 650 |
|
4 |
|a shuttle of polysulfide intermediates
|
| 700 |
1 |
|
|a Chen, Xiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Bo-Quan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Peng, Hong-Jie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Huang, Jia-Qi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xie, Jin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Qiang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 2 vom: 15. Jan.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2018
|g number:2
|g day:15
|g month:01
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201705219
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2018
|e 2
|b 15
|c 01
|