|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM278439780 |
| 003 |
DE-627 |
| 005 |
20231225020606.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231225s2018 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.201704436
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0928.xml
|
| 035 |
|
|
|a (DE-627)NLM278439780
|
| 035 |
|
|
|a (NLM)29178151
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Wang, Ziqi
|e verfasserin
|4 aut
|
| 245 |
1 |
2 |
|a A Metal-Organic-Framework-Based Electrolyte with Nanowetted Interfaces for High-Energy-Density Solid-State Lithium Battery
|
| 264 |
|
1 |
|c 2018
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 01.08.2018
|
| 500 |
|
|
|a Date Revised 30.09.2020
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
|
| 520 |
|
|
|a Solid-state batteries (SSBs) are promising for safer energy storage, but their active loading and energy density have been limited by large interfacial impedance caused by the poor Li+ transport kinetics between the solid-state electrolyte and the electrode materials. To address the interfacial issue and achieve higher energy density, herein, a novel solid-like electrolyte (SLE) based on ionic-liquid-impregnated metal-organic framework nanocrystals (Li-ILMOF) is reported, which demonstrates excellent electrochemical properties, including a high room-temperature ionic conductivity of 3.0 × 10-4 S cm-1 , an improved Li+ transference number of 0.36, and good compatibilities against both Li metal and active electrodes with low interfacial resistances. The Li-IL@MOF SLE is further integrated into a rechargeable Li|LiFePO4 SSB with an unprecedented active loading of 25 mg cm-2 , and the battery exhibits remarkable performance over a wide temperature range from -20 up to 150 °C. Besides the intrinsically high ionic conductivity of Li-IL@MOF, the unique interfacial contact between the SLE and the active electrodes owing to an interfacial wettability effect of the nanoconfined Li-IL guests, which creates an effective 3D Li+ conductive network throughout the whole battery, is considered to be the key factor for the excellent performance of the SSB
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a ionic liquids
|
| 650 |
|
4 |
|a lithium batteries
|
| 650 |
|
4 |
|a metal-organic frameworks
|
| 650 |
|
4 |
|a nanowetted interfaces
|
| 650 |
|
4 |
|a solid-like electrolytes
|
| 700 |
1 |
|
|a Tan, Rui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Hongbin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Luyi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hu, Jiangtao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Haibiao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Pan, Feng
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 30(2018), 2 vom: 15. Jan.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2018
|g number:2
|g day:15
|g month:01
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.201704436
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2018
|e 2
|b 15
|c 01
|