Hydrogen Uptake on Coordinatively Unsaturated Metal Sites in VSB-5 : Strong Binding Affinity Leading to High-Temperature D2/H2 Selectivity
We examine the adsorption of hydrogen and deuterium into the nanoporous nickel phosphate, VSB-5. On the basis of gas sorption analysis, VSB-5 exhibits one of the highest measured H2 heats of adsorption (HOA) for hydrogen (16 kJ/mol) yet reported. This high HOA is consistent with an unusually large r...
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Bibliographische Detailangaben
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 33(2017), 51 vom: 26. Dez., Seite 14586-14591
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| 1. Verfasser: |
Sharma, Amit
(VerfasserIn) |
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| Weitere Verfasser: |
Lawler, Keith V,
Wolffis, Jarod J,
Eckdahl, Christopher T,
McDonald, Cooper S,
Rowsell, Jesse L C,
FitzGerald, Stephen A,
Forster, Paul M |
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| Format: | Online-Aufsatz
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| Sprache: | English |
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| Veröffentlicht: |
2017
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids
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| Schlagworte: | Journal Article
Research Support, U.S. Gov't, Non-P.H.S. |
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