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231225s2018 xx |||||o 00| ||eng c |
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|a 10.1002/mrc.4677
|2 doi
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|a eng
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|a Saeed, Bahjat A
|e verfasserin
|4 aut
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|a NMR, MP2, and DFT study of thiophenoxyketenimines (o-thio-Schiff bases)
|b Determination of the preferred form
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|c 2018
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 20.11.2019
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Copyright © 2017 John Wiley & Sons, Ltd.
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|a Five new thiophenoxyketinimines have been synthesized. 1 H and 13 C NMR spectra as well as deuterium isotope effects on 13 C chemical shifts are determined, and spectra are assigned. DFT and MP2 calculations of both structures, chemical shifts, and isotope effects on chemical shifts are done. The combined analysis reveals that the compounds are primarily on a zwitterionic form with an NH+ and a S- group and with a little of the neutral form mixed in. Very strong intramolecular hydrogen bonding is found and very high NH chemical shifts are observed. The theoretical calculations show that calculations at the MP2 level are best to obtain correct "C═S" chemical shifts
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|a Journal Article
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|a MP2 and DFT calculations
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| 650 |
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|a isotope effects on chemical shifts
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|a tautomerism
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|a zwitterionic form
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|a Elias, Rita S
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Kamounah, Fadhil S
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Hansen, Poul Erik
|e verfasserin
|4 aut
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|i Enthalten in
|t Magnetic resonance in chemistry : MRC
|d 1985
|g 56(2018), 3 vom: 01. März, Seite 172-182
|w (DE-627)NLM098179667
|x 1097-458X
|7 nnns
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|g volume:56
|g year:2018
|g number:3
|g day:01
|g month:03
|g pages:172-182
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|u http://dx.doi.org/10.1002/mrc.4677
|3 Volltext
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