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231225s2017 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.7b03527
|2 doi
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|a eng
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|a Wang, Lu
|e verfasserin
|4 aut
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|a Rapidly Recoverable Thixotropic Hydrogels from the Racemate of Chiral OFm Monosubstituted Cyclo(Glu-Glu) Derivatives
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|c 2017
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|a Text
|b txt
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|a ƒaComputermedien
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|a Date Completed 01.08.2018
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|a Date Revised 01.08.2018
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Both chiral OFm monosubstituted cyclo(l-Glu-l-Glu) and cyclo(d-Glu-d-Glu) display a robust gelation ability in a variety of organic solvents and water. In contrast to an individual enantiomer, their racemate can form rapidly recoverable thixotropic hydrogels with a remarkably shorter thixotropic recovery time. This unexpected thixotropic behavior is induced by the random arrangement of d- and l-enantiomers in the cell units, leading to the formation of "pseudoracemate", noncrystalline self-assemblies in the resulting 3D fibrous network
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Jin, Xin
|e verfasserin
|4 aut
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|a Ye, Lin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Ai-Ying
|e verfasserin
|4 aut
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| 700 |
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|a Bezuidenhout, Deon
|e verfasserin
|4 aut
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| 700 |
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|a Feng, Zeng-Guo
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 33(2017), 48 vom: 05. Dez., Seite 13821-13827
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|g year:2017
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|g month:12
|g pages:13821-13827
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|u http://dx.doi.org/10.1021/acs.langmuir.7b03527
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