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231225s2017 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201703909
|2 doi
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|a pubmed25n0923.xml
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|a (NLM)29044794
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|a DE-627
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|e rakwb
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|a eng
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|a Yan, Chunshuang
|e verfasserin
|4 aut
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|a Engineering 2D Nanofluidic Li-Ion Transport Channels for Superior Electrochemical Energy Storage
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|c 2017
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 18.07.2018
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a Rational surface engineering of 2D nanoarchitectures-based electrode materials is crucial as it may enable fast ion transport, abundant-surface-controlled energy storage, long-term structural integrity, and high-rate cycling performance. Here we developed the stacked ultrathin Co3 O4 nanosheets with surface functionalization (SUCNs-SF) converted from layered hydroxides with inheritance of included anion groups (OH- , NO3- , CO32- ). Such stacked structure establishes 2D nanofluidic channels offering extra lithium storage sites, accelerated Li-ion transport, and sufficient buffering space for volume change during electrochemical processes. Tested as an anode material, this unique nanoarchitecture delivers high specific capacity (1230 and 1011 mAh g-1 at 0.2 and 1 A g-1 , respectively), excellent rate performance, and long cycle capability (1500 cycles at 5 A g-1 ). The demonstrated advantageous features by constructing 2D nanochannels in nonlayered materials may open up possibilities for designing high-power lithium ion batteries
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|a Journal Article
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|a energy storage
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|a lithium batteries
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|a nanofluidic channels
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|a stacked nanosheets
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|a two-dimensional
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|a Lv, Chade
|e verfasserin
|4 aut
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|a Zhu, Yue
|e verfasserin
|4 aut
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|a Chen, Gang
|e verfasserin
|4 aut
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|a Sun, Jingxue
|e verfasserin
|4 aut
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|a Yu, Guihua
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 29(2017), 46 vom: 27. Dez.
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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|g volume:29
|g year:2017
|g number:46
|g day:27
|g month:12
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|u http://dx.doi.org/10.1002/adma.201703909
|3 Volltext
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